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- W4385873184 abstract "Abstract Herein, we develop a new approach to directly access architecturally complex polycyclic indolines from readily available indoles and bicyclo[1.1.0]butanes (BCBs) through formal cycloaddition promoted by commercially available Lewis acids. The reaction proceeded through a stepwise pathway involving a nucleophilic addition of indoles to BCBs followed by an intramolecular Mannich reaction to form rigid indoline‐fused polycyclic structures, which resemble polycyclic indole alkaloids. This new reaction tolerated a wide range of indoles and BCBs, thereby allowing the one‐step construction of various rigid indoline polycycles containing up to four contiguous quaternary carbon centers." @default.
- W4385873184 created "2023-08-17" @default.
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- W4385873184 date "2023-08-25" @default.
- W4385873184 modified "2023-10-14" @default.
- W4385873184 title "Intermolecular Formal Cycloaddition of Indoles with Bicyclo[1.1.0]butanes by Lewis Acid Catalysis" @default.
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- W4385873184 doi "https://doi.org/10.1002/ange.202308606" @default.
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