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- W4385877608 abstract "Natural gas has been considered as a transiting fossil fuel into the future low-carbon world, improving air quality and reducing carbon intensity. The efficiency of purifying unconventional gas resources and recovering gas from hydrates via a CO2–CH4 exchange has attracted widespread attention in the scientific fields. However, the associated fluid flow, heat transfer, and hydrate reaction kinetics involving the mixed gas formation and dissociation are strongly needed in understanding the fundamental thermophysical properties. In this study, we designed a series of experiments employing depressurization and thermal stimulation to dissociate mixed CO2 + CH4 hydrates. We examined the kinetics, fluid production behavior, heat transfer characteristics, and separation factors during the hydrate formation and dissociation processes. The gas consumption and each phase saturation show a good consistency in all cases, however, the induction time was stochastic, ranging from 38 to 58 min. The separation factors were all less than 1.0, and the hydrate shows a strong selectivity to CH4 during the gas mixture hydrate formation process. The gas production increased with the decrease of the depressurization pressure. The peak value of the decomposition rate at 0.5 MPa is 0.2147 mol/min, which is 1.13 times that at 1.0 MPa and 13.5 times that at 1.5 MPa. Increasing decomposition temperature led to the rapid end of hydrate decomposition. The CO2 fraction was larger than that of CH4 during the hydrate dissociation process, and CO2 was easier to escape from the hydrate cage structure during the mixed gas hydrate decomposition process with decreasing pressure and increasing temperature." @default.
- W4385877608 created "2023-08-17" @default.
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- W4385877608 date "2023-08-16" @default.
- W4385877608 modified "2023-09-27" @default.
- W4385877608 title "Experimental Study on the Formation and Dissociation Characteristics of Mixed CO<sub>2</sub> + CH<sub>4</sub> Hydrates in Quartz Sand" @default.
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- W4385877608 doi "https://doi.org/10.1021/acs.energyfuels.3c01757" @default.
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