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- W4385895575 abstract "Degradation of acetamiprid (neonicotinoid group of pesticide) has been intensified by the application of hydrodynamic cavitation (HC) in combination with Fenton and photo-Fenton process using orifice plate and circular venturi as a cavitating device. Optimization of operating parameters using circular venturi has resulted in the optimum pH of 3 and the optimum acetamiprid concentration of 10 ppm. The inlet pressure to the cavitator was optimised at 5 bar for orifice plate and 6 bar for circular venturi. The molar ratio of acetamiprid to hydrogen peroxide and Fe2+ ions to H2O2 was optimised at 1:10 and 1:30 respectively. HC based combined strategies using circular venturi have resulted in the intensification of rate of degradation of acetamiprid. The reaction rate constant of 3.35 × 10-3 min−1, 4.80 × 10-3 min−1 and 16.17 × 10-3 min−1 with synergistic coefficient of 4.16, 1.78 and 1.39 was obtained in case of HC in combination with H2O2, Fenton’s reagent and photo-Fenton process respectively. Circular venturi has witnessed higher rate of degradation of acetamiprid as compared to orifice plate in case of HC and HC based combined strategies. Degradation by-products of acetamiprid produced during HC + photo-Fenton process have been identified successfully using LC-MS/MS analysis and the degradation mechanism has been proposed." @default.
- W4385895575 created "2023-08-18" @default.
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- W4385895575 date "2023-11-01" @default.
- W4385895575 modified "2023-09-26" @default.
- W4385895575 title "Combined strategy of hydrodynamic cavitation and Fenton chemistry for the intensified degradation of acetamiprid" @default.
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- W4385895575 doi "https://doi.org/10.1016/j.seppur.2023.124701" @default.
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