FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4385898005> ?p ?o ?g. }

• W4385898005 abstract "Abstract MXenes are a rapidly growing family of 2D transition metal carbides and nitrides that are promising for various applications, including energy storage and conversion, electronics, and healthcare. Hydrofluoric‐acid‐based etchants are typically used for large‐scale and high‐throughput synthesis of MXenes, which also leads to a mixture of surface terminations that impede MXene properties. Herein, a computational thermodynamic model with experimental validation is presented to explore the feasibility of fluorine‐free synthesis of MXenes with uniform surface terminations by dry selective extraction (DSE) from precursor MAX phases using iodine vapors. A range of MXenes and respective precursor compositions are systematically screened using first‐principles calculations to find candidates with high phase stability and low etching energy. A thermodynamic model based on the “CALculation of PHAse Diagrams” (CALPHAD) approach is further demonstrated, using Ti 3 C 2 I 2 as an example, to assess the Gibbs free energy of the DSE reaction and the state of the byproducts as a function of temperature and pressure. Based on the assessment, the optimal synthesis temperature and vapor pressure are predicted and further verified by experiments. This work opens an avenue for scalable, fluorine‐free dry synthesis of MXenes with compositions and surface chemistries that are not accessible using wet chemical etching." @default.
• W4385898005 created "2023-08-18" @default.
• W4385898005 creator A5001124246 @default.
• W4385898005 creator A5003015159 @default.
• W4385898005 creator A5079226352 @default.
• W4385898005 creator A5084188015 @default.
• W4385898005 creator A5091112732 @default.
• W4385898005 creator A5092653785 @default.
• W4385898005 creator A5092653786 @default.
• W4385898005 date "2023-10-03" @default.
• W4385898005 modified "2023-10-16" @default.
• W4385898005 title "Computationally Guided Synthesis of MXenes by Dry Selective Extraction" @default.
• W4385898005 cites W1948683553 @default.
• W4385898005 cites W1970127494 @default.
• W4385898005 cites W1975172861 @default.
• W4385898005 cites W1979544533 @default.
• W4385898005 cites W1980977510 @default.
• W4385898005 cites W1981368803 @default.
• W4385898005 cites W1992985800 @default.
• W4385898005 cites W2008319486 @default.
• W4385898005 cites W2014093718 @default.
• W4385898005 cites W2032799784 @default.
• W4385898005 cites W2044475690 @default.
• W4385898005 cites W2068131056 @default.
• W4385898005 cites W2083222334 @default.
• W4385898005 cites W2092207799 @default.
• W4385898005 cites W2093378101 @default.
• W4385898005 cites W2104196136 @default.
• W4385898005 cites W2241141269 @default.
• W4385898005 cites W2338599487 @default.
• W4385898005 cites W2516127619 @default.
• W4385898005 cites W2559458927 @default.
• W4385898005 cites W2580655056 @default.
• W4385898005 cites W2580793072 @default.
• W4385898005 cites W2748717829 @default.
• W4385898005 cites W2748956216 @default.
• W4385898005 cites W2766790390 @default.
• W4385898005 cites W2770765967 @default.
• W4385898005 cites W2810295309 @default.
• W4385898005 cites W2896104997 @default.
• W4385898005 cites W2904536479 @default.
• W4385898005 cites W2910661850 @default.
• W4385898005 cites W2912706548 @default.
• W4385898005 cites W2931627616 @default.
• W4385898005 cites W2932631126 @default.
• W4385898005 cites W2951813533 @default.
• W4385898005 cites W2962975009 @default.
• W4385898005 cites W3016170263 @default.
• W4385898005 cites W3038025793 @default.
• W4385898005 cites W3038791283 @default.
• W4385898005 cites W3039783515 @default.
• W4385898005 cites W3044354659 @default.
• W4385898005 cites W3081196004 @default.
• W4385898005 cites W3094059600 @default.
• W4385898005 cites W3096027022 @default.
• W4385898005 cites W3096648169 @default.
• W4385898005 cites W3112838175 @default.
• W4385898005 cites W3120277856 @default.
• W4385898005 cites W3125982301 @default.
• W4385898005 cites W3136059665 @default.
• W4385898005 cites W3156227411 @default.
• W4385898005 cites W3158495239 @default.
• W4385898005 cites W3171967633 @default.
• W4385898005 cites W3193369452 @default.
• W4385898005 cites W3195306529 @default.
• W4385898005 cites W3203833742 @default.
• W4385898005 cites W4210385306 @default.
• W4385898005 cites W4242273645 @default.
• W4385898005 cites W4289260927 @default.
• W4385898005 cites W4307566872 @default.
• W4385898005 cites W4308681132 @default.
• W4385898005 cites W4309116835 @default.
• W4385898005 cites W4318824925 @default.
• W4385898005 cites W4360609356 @default.
• W4385898005 cites W832976576 @default.
• W4385898005 doi "https://doi.org/10.1002/adma.202305200" @default.
• W4385898005 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37587765" @default.
• W4385898005 hasPublicationYear "2023" @default.
• W4385898005 type Work @default.
• W4385898005 citedByCount "0" @default.
• W4385898005 crossrefType "journal-article" @default.
• W4385898005 hasAuthorship W4385898005A5001124246 @default.
• W4385898005 hasAuthorship W4385898005A5003015159 @default.
• W4385898005 hasAuthorship W4385898005A5079226352 @default.
• W4385898005 hasAuthorship W4385898005A5084188015 @default.
• W4385898005 hasAuthorship W4385898005A5091112732 @default.
• W4385898005 hasAuthorship W4385898005A5092653785 @default.
• W4385898005 hasAuthorship W4385898005A5092653786 @default.
• W4385898005 hasBestOaLocation W43858980051 @default.
• W4385898005 hasConcept C121332964 @default.
• W4385898005 hasConcept C127413603 @default.
• W4385898005 hasConcept C146477669 @default.
• W4385898005 hasConcept C159985019 @default.
• W4385898005 hasConcept C171250308 @default.
• W4385898005 hasConcept C192562407 @default.
• W4385898005 hasConcept C2776106465 @default.
• W4385898005 hasConcept C2776453213 @default.
• W4385898005 hasConcept C42360764 @default.
• W4385898005 hasConcept C5335593 @default.
• W4385898005 hasConcept C97355855 @default.

• next