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- W4385922013 abstract "Autoignition temperature (AIT) data in the literature are frequently disparate and have high uncertainties. Examining the trend of AIT for chemical families that have well-defined homologous series can allow evaluation for internal consistency and provide phenomenological insight into the mechanisms that produce the observed trends, allowing engineers to better predict AIT for increasingly exotic compounds. The trend for the normal alkanes is well-studied and serves as a limiting case for other chemical families. A comprehensive examination of AIT trends for several chemical families reveals differences from the normal alkane family trend. AIT values from experimental measurements are presented and used, with literature values, to establish trends for several single-functional group chemical families, as well as propose and discuss phenomenological explanations for observed differences. Broader implications for these trends are also discussed along with best practices for evaluating and measuring AIT." @default.
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- W4385922013 date "2024-01-01" @default.
- W4385922013 modified "2023-10-14" @default.
- W4385922013 title "Autoignition temperature trends for various chemical families" @default.
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- W4385922013 doi "https://doi.org/10.1016/j.fuel.2023.129321" @default.
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