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- W4385951982 abstract "AbstractCircumscribing benzenoid polycyclic aromatic hydrocarbons was first introduced in 1982 under the topic of a periodic table for benzenoid hydrocarbons and isomer enumeration. This circumscribing process was rendered on benzene to successively generate coronene, circumcoronene, dicircumcornene, and so on as the first constant-isomer series. Subsequently, numerous benzenoid constant-isomer series were uncovered because of the coupling of the benzenoid periodic table (Table PAH6) and circumscribing. Circumscribing even carbon monocyclic polyenes produced [n]cyclacenes (n = number of hexagonal rings) which are monotier nanotubes. Starting with [n]cyclacenes and successive circumscribing generates (n,0) Zigzag nanotubes of increasing length. Successive circumscribing cycloparaphenylenes leads to (n,n) Armchair nanotubes of increasing length. Successive supercircumscribing cycloparaphenylenes leads to total-resonant-sextet Armchair nanotubes of maximum stability. Circumscribing polycyclic conjugated systems was subsequently introduced for other ring sizes. Circumscribing polycyclic hydrocarbons with a combination of pentagonal and hexagonal rings leads to fullerenes when 12 pentagonal ring is reached. Generation of altans is a specialised type of circumscribing in which the encircling annulene is attached via its alternate degree-2 vertices to the degree-2 vertices of the core structure. We show that monocapped nanotubes are circumscribed altans.KEYWORDS: Circumscribingmonocapped nanotubesaltanseigenvalueseigenvectors Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by UM Board of Curators [grant number K0906077]." @default.
- W4385951982 created "2023-08-18" @default.
- W4385951982 creator A5049599890 @default.
- W4385951982 date "2023-08-17" @default.
- W4385951982 modified "2023-10-05" @default.
- W4385951982 title "The evolution of the principle of circumscribing" @default.
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- W4385951982 doi "https://doi.org/10.1080/00268976.2023.2245485" @default.
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