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- W4385963486 abstract "In the title compounds, N,N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol tribromide (1/1), C4H9NO·C4H10NO+·Br3- or [(C4H9NO)·(C4H10NO)](Br3), (I), N,N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol di-bromido-iodate (1/1), C4H9NO·C4H10NO+·Br2I- or [(C4H9NO)·(C4H10NO)](Br2I), (II), and N,N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol di-chlorido-iodate (1/1), C4H9NO·C4H10NO+·Cl2I- or [(C4H9NO)·(C4H10NO)]·(Cl2I), (III), all the anions are almost linear in geometry and all the cations, except for the methyl H atoms, are essentially planar. In the crystal structure of (I), the cations are linked by pairs of C-H⋯O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. These dimers also exhibit O-H⋯O hydrogen bonding. Dimerized cation pairs and anions are arranged in columns along the a axis. In the crystal of (II), the cations are linked by pairs of O-H⋯O and C-H⋯O hydrogen bonds, forming an R44(14) ring motif. These groups of cations and the anions form individual columns along the a axis and jointly reside in planes roughly parallel to (011). In the crystal of (III), cations and anions also form columns parallel to the a axis, resulting in layers parallel to the (020) plane. Furthermore, the crystal structures of (I), (II) and (III) are consolidated by strong halogen (Br and/or I and/or Cl)⋯H and weak van der Waals inter-actions. In addition to the structural evaluation, a Hirshfeld surface analysis was carried out." @default.
- W4385963486 created "2023-08-18" @default.
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- W4385963486 date "2023-07-04" @default.
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- W4385963486 title "Crystal structures and Hirshfeld surface analyses of <i>N</i>,<i>N</i>-dimethylacetamide–1-(dimethyl-λ<sup>4</sup>-azanylidene)ethan-1-ol tribromide (1/1), <i>N</i>,<i>N</i>-dimethylacetamide–1-(dimethyl-λ<sup>4</sup>-azanylidene)ethan-1-ol dibromidoiodate (1/1) and <i>N</i>,<i>N</i>-dimethylacetamide–1-(dimethyl-λ<sup>4</sup>-azanylidene)ethan-1-ol dichloridoiodate (1/1)" @default.
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- W4385963486 doi "https://doi.org/10.1107/s2056989023005509" @default.
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