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• W4385972153 abstract "We report a pressure effect on a heat-storage material, Al-substituted lambda-trititanium-pentoxide (λ-AlxTi3−xO5, 0 < x ≤ 0.29), showing a phase transition to β-AlxTi3−xO5 by pressure application. The transition pressure is 23 MPa and 43 MPa for x = 0.01 and 0.04, respectively, which are available pressures for practical applications. First-principles electronic structure calculations of λ-Al0.25Ti2.75O5 were conducted to investigate the substitution site selectivity of the Al3+ ion and the substitution effect on the pressure-induced phase transition. We report Al-substituted lambda-trititanium-pentoxide (λ-AlxTi3−xO5), which shows a phase transition to β-AlxTi3−xO5 by pressure application. The transition pressures are 23 and 43 MPa for x = 0.01 and 0.04, respectively, which are available pressures for practical applications. First-principles calculations of λ-Al0.25Ti2.75O5 were conducted to investigate the Al-substitution site selectivity and the substitution effect on the pressure-induced phase transition." @default.
• W4385972153 created "2023-08-19" @default.
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• W4385972153 date "2023-09-05" @default.
• W4385972153 modified "2023-10-17" @default.
• W4385972153 title "Observation of a Pressure Effect on an Al-Substituted λ-Ti₃O₅ Heat-Storage Material" @default.
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• W4385972153 doi "https://doi.org/10.1246/cl.230244" @default.
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