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- W4385986588 abstract "Abstract Cellulose has experienced a renaissance as a precursor for carbon fibers (CFs). However, cellulose possesses intrinsic challenges as precursor substrate such as typically low carbon yield. This study examines the interplay of strategies to increase the carbonization yield of (ligno-) cellulosic fibers manufactured via a coagulation process. Using Design of Experiments, this article assesses the individual and combined effects of diammonium hydrogen phosphate (DAP), lignin, and CO $$_{2}$$ <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML> <mml:msub> <mml:mrow /> <mml:mn>2</mml:mn> </mml:msub> </mml:math> activation on the carbonization yield and properties of cellulose-based carbon fibers. Synergistic effects are identified using the response surface methodology. This paper evidences that DAP and lignin could affect cellulose pyrolysis positively in terms of carbonization yield. Nevertheless, DAP and lignin do not have an additive effect on increasing the yield. In fact, combined DAP and lignin can affect negatively the carbonization yield within a certain composition range. Further, the thermogravimetric CO $$_{2}$$ <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML> <mml:msub> <mml:mrow /> <mml:mn>2</mml:mn> </mml:msub> </mml:math> adsorption of the respective CFs was measured, showing relatively high values (ca. 2 mmol/g) at unsaturated pressure conditions. The CFs were microporous materials with potential applications in gas separation membranes and CO $$_{2}$$ <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML> <mml:msub> <mml:mrow /> <mml:mn>2</mml:mn> </mml:msub> </mml:math> storage systems. Graphical abstract" @default.
- W4385986588 created "2023-08-19" @default.
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- W4385986588 date "2023-08-18" @default.
- W4385986588 modified "2023-10-14" @default.
- W4385986588 title "Interdependent factors influencing the carbon yield, structure, and CO$$_{2}$$ adsorption capacity of lignocellulose-derived carbon fibers using multiple linear regression" @default.
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- W4385986588 doi "https://doi.org/10.1007/s42823-023-00591-3" @default.
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