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- W4386003141 abstract "A Pt nanoparticle (Pt(w-MI)) film was prepared on a fluorine-doped tin oxide (FTO) conducting substrate from a precursor solution containing H2PtCl6 in a mixed solvent of methanol/1-methyimidasol (MI) (3:1 v/v) by a mixed metal-imidazole casting (MiMIC) method. The Pt(w-MI) film is the uniformly dense morphology composed of compacted and well-connected Pt nanoparticles compared to the hollow morphology for the Pt(w/o-MI) film fabricated without MI. The Pt(w-MI)/FTO cathode showed efficient and durable HER activities, generating a current density of 10 mA cm−2 at an overpotential (η10) of 198 mV, a Tafel slope of 128 mV dec−1, and a Pt mass activity of 0.11 A cm−2 mgPt−1 at 200 mV in the alkaline medium (1.0 M KOH solutions, pH = 14.0), which are substantially higher than the Pt(w/o-MI)/FTO and the commercially available Pt-loaded carbon (Pt/C) on the FTO cathodes. The mechanism of the efficient HER for the Pt(w-MI)/FTO cathode was investigated by an electrochemical impedance spectroscopic (EIS) method. The bulk charge transport in the Pt(w-MI) film is faster than that in the Pt(w/o-MI) film, ascribed to the compacted and well-connected Pt nanoparticles for Pt(w-MI). Furthermore, the surface proton reduction for Pt(w-MI) is also faster than that for Pt(w/o-MI), affording the efficient HER activity for Pt(w-MI) compared to Pt(w/o-MI)." @default.
- W4386003141 created "2023-08-20" @default.
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- W4386003141 date "2023-08-01" @default.
- W4386003141 modified "2023-10-12" @default.
- W4386003141 title "Mechanistic insight into efficient electrocatalysis for hydrogen evolution by a platinum film prepared on an FTO electrode using a mixed metal-imidazole casting method" @default.
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- W4386003141 doi "https://doi.org/10.1016/j.ijhydene.2023.08.001" @default.
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