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- W4386003737 abstract "In this work, grafting of AC/MIL-101(Cr) hybrid sample using acidic deep eutectic solvent (DES) was performed to enhance the acidity and catalytic activity for the acetylation reaction of glycerol. DESs are green solvents and have many advantages such as easy preparation with the mixing of two or three components, high biodegradability, environmentally friendly nature. The synthesized hybrid materials, AC/MIL-101 and AC/MIL-101/DES were characterized using different characterization methods such as XRD, TGA, N2 adsorption, FTIR, SEM-EDS, XPS and potentiometric titration to elucidate the structure of the material. AC/MIL-101 and AC/MIL-101/DES composite catalysts were used in acetylation of glycerol reaction as heterogeneous catalysts. AC/MIL-101/DES sample gave higher triacetin (TAG) selectivity and glycerol conversion in the acetylation reaction of glycerol. The catalytic activity was increased via incorporation of DES into AC/MIL-101 structure. The acidity value increased after incorporation of DES into AC/MIL-101 structure, so the TAG selectivity value increased from 1.20 to 3.31% at temperature of 90°C. The maximum conversion of glycerol was found as 100% and TAG selectivity was increased up to 15.88% by changing of the process conditions. In addition, AC/MIL-101/DES sample could be regenerated and recycled without any decrement in TAG selectivity and glycerol conversion values." @default.
- W4386003737 created "2023-08-20" @default.
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- W4386003737 date "2023-12-01" @default.
- W4386003737 modified "2023-10-17" @default.
- W4386003737 title "Deep eutectic solvent incorporated AC/MIL-101 hybrid material catalysts for the production of fuel additives (acetins) from by-product glycerol" @default.
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- W4386003737 doi "https://doi.org/10.1016/j.mtsust.2023.100499" @default.
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