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• W4386017183 abstract "Controlling the reaction selectivity by use of rationally designed catalysts provides high yields of desired products rendering the process more efficient and sustainable. In this study, we investigated a series of isoreticular zeolites (Al-IPC-n, n = 2, 4, 6, and 7), in the synthesis of lactide from L-Lactic acid as an intermediate for the polylactic acid production. Catalytic tests allowed a thorough understanding of the structure-acidity-activity relationship and the control of the shape selectivity. The lactide and the dimers of the lactic acid were obtained in one step with a high selectivity (>55% for lactide and >70% for the dimer of the lactic). The selectivity to L,L-lactide was comparable with that on more acidic commercial BEA. A balance between the acidity and the pore size afforded high yields of the dimer, avoiding the poisoning of the catalyst and the production of the larger oligomers." @default.
• W4386017183 created "2023-08-21" @default.
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• W4386017183 date "2023-09-01" @default.
• W4386017183 modified "2023-10-17" @default.
• W4386017183 title "Synthesis of lactide from L-Lactic acid over iso-reticular zeolites derived from Al-UTL" @default.
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• W4386017183 doi "https://doi.org/10.1016/j.apcata.2023.119379" @default.
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