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• W4386021977 startingPage "11697" @default.
• W4386021977 abstract "The electrochemical reduction of CO2 (CO2ER) holds great promise as a method to achieve carbon neutrality and revolutionize the utilization of fossil fuels. Advanced catalysts used in CO2ER have demonstrated the ability to generate valuable multi-carbon products through the formation of carbon–carbon (C–C) bonds. Previous research has predominantly focused on C–C formation by dimerizing *CO or coupling *CO with other *C1 intermediates. However, the potential coupling of CO2 with *C1 intermediates has not been explored experimentally or theoretically despite CO2 being the exclusive reactant in CO2ER and having a high concentration. This study employed DFT calculations and a constant electrode potential model to investigate the possibility of CO2 + *C1 couplings on Cu(100) surfaces. Surprisingly, the results indicate that CO2 can serve as a favorable reagent for C–C bond formation, surpassing the reactivity of *CO under alkaline conditions. The enhanced reactivity of CO2 compared to that of *CO was elucidated based on a barrier decomposition analysis. Experimental validation was conducted to confirm these theoretical results." @default.
• W4386021977 created "2023-08-22" @default.
• W4386021977 creator A5019707917 @default.
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• W4386021977 date "2023-08-21" @default.
• W4386021977 modified "2023-09-26" @default.
• W4386021977 title "Identification of CO₂ as a Reactive Reagent for C–C Bond Formation via Copper-Catalyzed Electrochemical Reduction" @default.
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