FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386050887> ?p ?o ?g. }

• W4386050887 abstract "The sterically demanding N-heterocyclic carbene ITr (N,N'-bis(triphenylmethyl)imidazolylidene) was employed for the preparation of novel trigonal zinc(II) complexes of the type [ZnX2(ITr)] (X = Cl (1), Br (2), I (3)), for which the low coordination mode was confirmed in both solution and the solid state. Because of the atypical coordination geometry, the reactivity of 1-3 was studied in detail, using partial or exhaustive halide exchange and halide abstraction reactions to access [ZnLCl(ITr)] (L = carbazolate (4), 3,6-di-tert-butyl-carbazolate (5), phenoxazine (6) and phenothiazine (7)), [Zn(bdt)(ITr)] (bdt = benzene-1,2-dithiolate) (8) and cationic [Zn(2-X)(ITr)]2[BPhF4]2 (X = Cl (9), Br (10), I (11)), all of which were isolated and structurally characterized. Importantly, for all complexes 4-11, the trigonal coordination environment of the ZnII ion is maintained, demonstrating a highly stabilizing effect due to the steric demand of the ITr ligand, which protects the metal center from further ligand association. In addition, complexes 1-3 and 8-11 show long-lived luminescence from triplet excited states in the solid state at room temperature according to our photophysical studies. Our quantum chemical DFT/MRCI calculations reveal that the phosphorescence of 8 originates from a locally excited triplet state on the bdt ligand. They further suggest that the phenyl substituents of ITr are photochemically not innocent but can coordinate to the electron deficient metal center of this trigonal complex in the excited state." @default.
• W4386050887 created "2023-08-23" @default.
• W4386050887 creator A5003564111 @default.
• W4386050887 creator A5019005150 @default.
• W4386050887 creator A5034760458 @default.
• W4386050887 creator A5036083100 @default.
• W4386050887 creator A5038734674 @default.
• W4386050887 creator A5082499482 @default.
• W4386050887 creator A5092807968 @default.
• W4386050887 date "2023-08-22" @default.
• W4386050887 modified "2023-09-27" @default.
• W4386050887 title "Synthesis, Structural Characterization and Phosphorescence Properties of Trigonal Zn(II) Carbene Complexes" @default.
• W4386050887 doi "https://doi.org/10.26434/chemrxiv-2023-2vk8w" @default.
• W4386050887 hasPublicationYear "2023" @default.
• W4386050887 type Work @default.
• W4386050887 citedByCount "0" @default.
• W4386050887 crossrefType "posted-content" @default.
• W4386050887 hasAuthorship W4386050887A5003564111 @default.
• W4386050887 hasAuthorship W4386050887A5019005150 @default.
• W4386050887 hasAuthorship W4386050887A5034760458 @default.
• W4386050887 hasAuthorship W4386050887A5036083100 @default.
• W4386050887 hasAuthorship W4386050887A5038734674 @default.
• W4386050887 hasAuthorship W4386050887A5082499482 @default.
• W4386050887 hasAuthorship W4386050887A5092807968 @default.
• W4386050887 hasBestOaLocation W43860508871 @default.
• W4386050887 hasConcept C111592845 @default.
• W4386050887 hasConcept C115624301 @default.
• W4386050887 hasConcept C116569031 @default.
• W4386050887 hasConcept C121332964 @default.
• W4386050887 hasConcept C142724271 @default.
• W4386050887 hasConcept C161790260 @default.
• W4386050887 hasConcept C170493617 @default.
• W4386050887 hasConcept C171560689 @default.
• W4386050887 hasConcept C178790620 @default.
• W4386050887 hasConcept C179104552 @default.
• W4386050887 hasConcept C181500209 @default.
• W4386050887 hasConcept C181817918 @default.
• W4386050887 hasConcept C183882617 @default.
• W4386050887 hasConcept C185544564 @default.
• W4386050887 hasConcept C185592680 @default.
• W4386050887 hasConcept C188027245 @default.
• W4386050887 hasConcept C198819137 @default.
• W4386050887 hasConcept C201194858 @default.
• W4386050887 hasConcept C204787440 @default.
• W4386050887 hasConcept C2776910235 @default.
• W4386050887 hasConcept C2777164566 @default.
• W4386050887 hasConcept C2781083472 @default.
• W4386050887 hasConcept C32909587 @default.
• W4386050887 hasConcept C544153396 @default.
• W4386050887 hasConcept C55493867 @default.
• W4386050887 hasConcept C61126556 @default.
• W4386050887 hasConcept C62520636 @default.
• W4386050887 hasConcept C71240020 @default.
• W4386050887 hasConcept C71924100 @default.
• W4386050887 hasConcept C75473681 @default.
• W4386050887 hasConcept C76766466 @default.
• W4386050887 hasConcept C8010536 @default.
• W4386050887 hasConcept C91881484 @default.
• W4386050887 hasConceptScore W4386050887C111592845 @default.
• W4386050887 hasConceptScore W4386050887C115624301 @default.
• W4386050887 hasConceptScore W4386050887C116569031 @default.
• W4386050887 hasConceptScore W4386050887C121332964 @default.
• W4386050887 hasConceptScore W4386050887C142724271 @default.
• W4386050887 hasConceptScore W4386050887C161790260 @default.
• W4386050887 hasConceptScore W4386050887C170493617 @default.
• W4386050887 hasConceptScore W4386050887C171560689 @default.
• W4386050887 hasConceptScore W4386050887C178790620 @default.
• W4386050887 hasConceptScore W4386050887C179104552 @default.
• W4386050887 hasConceptScore W4386050887C181500209 @default.
• W4386050887 hasConceptScore W4386050887C181817918 @default.
• W4386050887 hasConceptScore W4386050887C183882617 @default.
• W4386050887 hasConceptScore W4386050887C185544564 @default.
• W4386050887 hasConceptScore W4386050887C185592680 @default.
• W4386050887 hasConceptScore W4386050887C188027245 @default.
• W4386050887 hasConceptScore W4386050887C198819137 @default.
• W4386050887 hasConceptScore W4386050887C201194858 @default.
• W4386050887 hasConceptScore W4386050887C204787440 @default.
• W4386050887 hasConceptScore W4386050887C2776910235 @default.
• W4386050887 hasConceptScore W4386050887C2777164566 @default.
• W4386050887 hasConceptScore W4386050887C2781083472 @default.
• W4386050887 hasConceptScore W4386050887C32909587 @default.
• W4386050887 hasConceptScore W4386050887C544153396 @default.
• W4386050887 hasConceptScore W4386050887C55493867 @default.
• W4386050887 hasConceptScore W4386050887C61126556 @default.
• W4386050887 hasConceptScore W4386050887C62520636 @default.
• W4386050887 hasConceptScore W4386050887C71240020 @default.
• W4386050887 hasConceptScore W4386050887C71924100 @default.
• W4386050887 hasConceptScore W4386050887C75473681 @default.
• W4386050887 hasConceptScore W4386050887C76766466 @default.
• W4386050887 hasConceptScore W4386050887C8010536 @default.
• W4386050887 hasConceptScore W4386050887C91881484 @default.
• W4386050887 hasFunder F4320308269 @default.
• W4386050887 hasFunder F4320320879 @default.
• W4386050887 hasLocation W43860508871 @default.
• W4386050887 hasOpenAccess W4386050887 @default.
• W4386050887 hasPrimaryLocation W43860508871 @default.
• W4386050887 hasRelatedWork W2029153478 @default.
• W4386050887 hasRelatedWork W2128275295 @default.
• W4386050887 hasRelatedWork W2513682993 @default.
• W4386050887 hasRelatedWork W2790640852 @default.

• next