FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386054503> ?p ?o ?g. }

• W4386054503 endingPage "7022" @default.
• W4386054503 startingPage "7006" @default.
• W4386054503 abstract "In this work, a novel, straightforward, robust, fast, and organocatalyst-mediated phospha-Michael reaction (OCPMR) was developed for the addition of phosphorus nucleophiles to electron-deficient alkynes. Several P–H bond-bearing compounds with either fully aliphatic or aromatic units were utilized for this newly developed reaction, and it was found that phosphorous species containing only aromatic groups reacted with activated alkynes within 5 min at room temperature. The reaction led to a fast double-addition of the phosphorous compounds to the triple bond of the alkynes. An in-depth analysis of the reaction mechanism and selectivity of this OCPMR was performed using computational methods. Using the developed method, double-phosphorylated allyl-functional monomers were synthesized and subsequently used for the synthesis of linear and crosslinked polymers via thiol-ene photopolymerization. The thermoset materials exhibited LOI values as high as 26.4%. We also showed that polyesters having electron-deficient triple bonds could be easily functionalized with the P–H bond-bearing compounds. The synthetic method proposed herein promises easy and fast P–C bond formation under mild reaction conditions, and it is a straightforward method for the synthesis of phosphorus-containing monomers, linear or crosslinked polymers, and for polymer post-functionalization. We believe this feature will be of great interest not only to material chemists and polymer scientists but also to organic chemists, pharmaceutical researchers, etc." @default.
• W4386054503 created "2023-08-23" @default.
• W4386054503 creator A5015410968 @default.
• W4386054503 creator A5023658168 @default.
• W4386054503 creator A5036587126 @default.
• W4386054503 creator A5039315714 @default.
• W4386054503 creator A5048591583 @default.
• W4386054503 creator A5069397352 @default.
• W4386054503 creator A5079814223 @default.
• W4386054503 creator A5081177156 @default.
• W4386054503 date "2023-08-22" @default.
• W4386054503 modified "2023-10-15" @default.
• W4386054503 title "New Horizon in Phospha-Michael Reaction: Ultrafast Double Addition of P–H Bond-Bearing Nucleophiles to Electron-Deficient Triple Bonds and Its Use for Functional Monomer Synthesis and Polymer Modification" @default.
• W4386054503 cites W1831306002 @default.
• W4386054503 cites W1966949133 @default.
• W4386054503 cites W1978940199 @default.
• W4386054503 cites W1992173555 @default.
• W4386054503 cites W1997151511 @default.
• W4386054503 cites W2027033941 @default.
• W4386054503 cites W2050883817 @default.
• W4386054503 cites W2056182770 @default.
• W4386054503 cites W2064520319 @default.
• W4386054503 cites W2068666786 @default.
• W4386054503 cites W2085336624 @default.
• W4386054503 cites W2086509002 @default.
• W4386054503 cites W2087597968 @default.
• W4386054503 cites W2090191036 @default.
• W4386054503 cites W2098944322 @default.
• W4386054503 cites W2122411191 @default.
• W4386054503 cites W2146110140 @default.
• W4386054503 cites W2160026850 @default.
• W4386054503 cites W2312562110 @default.
• W4386054503 cites W2318371517 @default.
• W4386054503 cites W2418389840 @default.
• W4386054503 cites W2513363649 @default.
• W4386054503 cites W2545166242 @default.
• W4386054503 cites W2599366142 @default.
• W4386054503 cites W2747710025 @default.
• W4386054503 cites W2763684786 @default.
• W4386054503 cites W2801099489 @default.
• W4386054503 cites W2803635950 @default.
• W4386054503 cites W2898923785 @default.
• W4386054503 cites W2914139161 @default.
• W4386054503 cites W2942663916 @default.
• W4386054503 cites W2947930314 @default.
• W4386054503 cites W2951266867 @default.
• W4386054503 cites W2951958366 @default.
• W4386054503 cites W2996029997 @default.
• W4386054503 cites W2997854042 @default.
• W4386054503 cites W3000473467 @default.
• W4386054503 cites W3009106060 @default.
• W4386054503 cites W3016013915 @default.
• W4386054503 cites W3016462764 @default.
• W4386054503 cites W3024412502 @default.
• W4386054503 cites W3047747683 @default.
• W4386054503 cites W3132997989 @default.
• W4386054503 cites W3137739827 @default.
• W4386054503 cites W3151408156 @default.
• W4386054503 cites W3154756223 @default.
• W4386054503 cites W3156584888 @default.
• W4386054503 cites W3158815785 @default.
• W4386054503 cites W3164824918 @default.
• W4386054503 cites W3198640072 @default.
• W4386054503 cites W3209024706 @default.
• W4386054503 cites W3214597065 @default.
• W4386054503 cites W3214736453 @default.
• W4386054503 cites W3217367136 @default.
• W4386054503 cites W4206746468 @default.
• W4386054503 cites W4221052165 @default.
• W4386054503 cites W4286716891 @default.
• W4386054503 cites W4302292655 @default.
• W4386054503 cites W4307045758 @default.
• W4386054503 cites W4313528335 @default.
• W4386054503 cites W4321167647 @default.
• W4386054503 doi "https://doi.org/10.1021/acs.macromol.3c00625" @default.
• W4386054503 hasPublicationYear "2023" @default.
• W4386054503 type Work @default.
• W4386054503 citedByCount "0" @default.
• W4386054503 crossrefType "journal-article" @default.
• W4386054503 hasAuthorship W4386054503A5015410968 @default.
• W4386054503 hasAuthorship W4386054503A5023658168 @default.
• W4386054503 hasAuthorship W4386054503A5036587126 @default.
• W4386054503 hasAuthorship W4386054503A5039315714 @default.
• W4386054503 hasAuthorship W4386054503A5048591583 @default.
• W4386054503 hasAuthorship W4386054503A5069397352 @default.
• W4386054503 hasAuthorship W4386054503A5079814223 @default.
• W4386054503 hasAuthorship W4386054503A5081177156 @default.
• W4386054503 hasConcept C112423150 @default.
• W4386054503 hasConcept C115537861 @default.
• W4386054503 hasConcept C12556323 @default.
• W4386054503 hasConcept C147789679 @default.
• W4386054503 hasConcept C161790260 @default.
• W4386054503 hasConcept C166940927 @default.
• W4386054503 hasConcept C178790620 @default.
• W4386054503 hasConcept C178907741 @default.
• W4386054503 hasConcept C185592680 @default.
• W4386054503 hasConcept C188027245 @default.
• W4386054503 hasConcept C196099240 @default.

• next