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- W4386090112 abstract "A stimuli-responsive luminophore embedding an overcrowded bistricyclic aromatic ene structure with a heptagon═hexagon central ring, DCHA-TRZ, has been designed and synthesized. In a single-crystalline solid, DCHA-TRZ constructed a supramolecular organic framework (SOF) including n-hexane molecules as a guest molecule. The crystalline SOF (α phase) exhibited reversible crystalline (α)-to-amorphous-to-crystalline (α) solid-state phase transitions triggered by external stimuli of mechanical grinding and treatment with an n-hexane solvent, in which release and inclusion of the guest molecules played an important role. Moreover, the thermal annealing of the amorphous ground solid afforded a bluish-green-emitting solid with a different crystalline phase (β). The combination of the three external stimuli of mechanical grinding, thermal annealing, and solvent treatment enables the reversible and cyclical phase transitions among three solid-state phases (crystalline α and β and amorphous) under concomitant emission color changes." @default.
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- W4386090112 date "2023-08-23" @default.
- W4386090112 modified "2023-10-18" @default.
- W4386090112 title "Multiple Stimuli-Responsive Supramolecular Organic Framework under Concomitant Emission Color Changes" @default.
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- W4386090112 doi "https://doi.org/10.1021/acs.jpcc.3c03459" @default.
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