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- W4386091856 abstract "Abstract This study presents a novel halogen dance reaction using 4,5‐dibromo‐2,4’‐bithiazole, which demonstrates a long‐range effect. The reaction involves the migration of a bromo group from the C5‐position to the C2’‐position of another thiazole ring when treated with lithium hexamethyldisilazide (LiHMDS), resulting in the formation of a non‐symmetric brominated bithiazole. In contrast, the base‐induced C2’‐bromination of 4‐bromobithiazole was found to be inefficient in synthesizing the desired brominated bithiazole due to its poor deprotonation selectivity." @default.
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- W4386091856 date "2023-08-23" @default.
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- W4386091856 title "Synthesis of 2’,4‐Dibromo‐2,4’‐bithiazole Using Novel Long‐range Halogen Dance Reaction" @default.
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- W4386091856 doi "https://doi.org/10.1002/slct.202302632" @default.
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