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• W4386097568 abstract "The asymmetric units of the isostructural compounds (1,4,8,11-tetraazacyclotetradecane-κ 4 N )nickel(II) tetraiodidocadmate(II), [Ni(C 10 H 24 N 4 )][CdI 4 ] ( I ), and triiodido-1κ 3 I -μ-iodido-(1,4,8,11-tetraazacyclotetradecane-2κ 4 N )cadmium(II)zinc(II), [CdZnI 4 (C 10 H 24 N 4 )] ( II ) (C 10 H 24 N 4 = 1,4,8,11-tetraazacyclotetradecane, cyclam, L ), consist of the centrosymmetric macrocyclic cation [ M ( L )] 2+ [ M = Ni II or Zn II ] with the metal ion lying on a twofold screw axis, and the tetraiodocadmate anion [CdI 4 ] 2− located on the mirror plane. In I , the anion acts as an uncoordinated counter-ion while in II it is bound to the Zn II atom via one of the iodide atoms, thus forming an electroneutral heterobimetallic complex [Zn( L )(CdI 4 )]. The Ni II and Zn II ions are coordinated in a square-planar manner by the four secondary N atoms of the macrocyclic ligand L , which adopts the most energetically stable trans -III conformation. The [CdI 4 ] 2− anions in I and II are structurally very similar and represent slightly deformed tetrahedrons with average Cd—I bond lengths and I—Cd—I angles of ca 2.79 Å and 109.6°, respectively. The supramolecular organization of the complexes under consideration in the crystals is very similar and is determined by the hydrogen-bonding interactions between the secondary amino groups of the ligand L in the [ M ( L )] 2+ cations and iodide atoms of the [CdI 4 ] 2− anion. In particular, the alternating cations and anions form chains running along the b- axis direction that are arranged into di-periodic sheets oriented parallel to the (101) and (overline{1}01) planes. Because both kinds of sheets are built from the same cations and anions, this feature provides the three-dimensional coherence of the crystals of I and II ." @default.
• W4386097568 created "2023-08-24" @default.
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• W4386097568 date "2023-08-23" @default.
• W4386097568 modified "2023-09-29" @default.
• W4386097568 title "Crystal structures of the complexes containing macrocyclic cations [<i>M</i>(cyclam)]²⁺ (<i>M</i> = Ni, Zn) and tetraiodidocadmate(2–) anion" @default.
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• W4386097568 doi "https://doi.org/10.1107/s2056989023007004" @default.
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