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- W4386119441 endingPage "41503" @default.
- W4386119441 startingPage "41494" @default.
- W4386119441 abstract "The poly(2,5-dihydroxy-1,4-benzoquinone-3,6-methylene) (denoted as PDBM) capable of reversible coordination/uncoordination with both mono- and multivalent cations in aqueous electrolytes is desired to develop safe, sustainable, and cost-effective aqueous rechargeable batteries (ARBs). However, the comprehensive mechanism between the electrochemical performance of PDBM and properties of these metal cations is unclear. Herein, we initially demonstrate the universality of PDBM to reversibly coordinate/uncoordinate with various cations (Na+, Mg2+, Ca2+, Zn2+, Al3+, etc.) with high specific capacities (>200 mA h g-1), high rate capabilities (∼20 C), and long cycling life (5000 cycles). Additionally, an unprecedented ion-coordination mechanism is presented: the monovalent cations prefer to occupy the in-plane sites with respect to the benzene rings of PDBM during the electrochemical reduced process, while the multivalent cations with the larger charge density tend to occupy the out-of-plane sites, which can use more active sites in the PDBM molecule and deliver the higher specific capacities. Meanwhile, the redox potential of PDBM decreases with the decrease in the binding energy between metal cations and PDBM molecules. The universality of PDBM to numerous cations is beneficial to design high-safety, low-cost, and long-lifespan ARBs for large-scale energy storage systems by modulating the aqueous electrolytes." @default.
- W4386119441 created "2023-08-25" @default.
- W4386119441 creator A5007290693 @default.
- W4386119441 creator A5007971223 @default.
- W4386119441 creator A5036349580 @default.
- W4386119441 creator A5045125415 @default.
- W4386119441 creator A5081641327 @default.
- W4386119441 creator A5085826877 @default.
- W4386119441 date "2023-08-24" @default.
- W4386119441 modified "2023-09-26" @default.
- W4386119441 title "Universality of Benzoquinone-based Anodes toward Various Metal Cations in Aqueous Rechargeable Batteries" @default.
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- W4386119441 doi "https://doi.org/10.1021/acsami.3c07147" @default.
- W4386119441 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37616444" @default.
- W4386119441 hasPublicationYear "2023" @default.
- W4386119441 type Work @default.