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- W4386135059 abstract "Abstract Sulfonyl and sulfonimidoyl fluorides are versatile substrates in organic synthesis and medicinal chemistry. However, they have been exclusively used as S(VI) + electrophiles for defluorinative ligations. Converting sulfonyl and sulfonimidoyl fluorides to S(VI) radicals is challenging and underexplored due to the strong bond dissociation energy of S VI −F and high reduction potentials, but once achieved would enable dramatically expanded synthetic utility and downstream applications. In this report, we disclose a general platform to address this issue through cooperative organosuperbase activation and photoredox catalysis. Vinyl sulfones and sulfoximines are obtained with excellent E selectivity under mild conditions by coupling reactions with alkenes. The synthetic utility of this method in the preparation of functional polymers and dyes is also demonstrated." @default.
- W4386135059 created "2023-08-25" @default.
- W4386135059 creator A5008053838 @default.
- W4386135059 creator A5010535174 @default.
- W4386135059 creator A5014699817 @default.
- W4386135059 creator A5036764196 @default.
- W4386135059 creator A5072147423 @default.
- W4386135059 creator A5081567950 @default.
- W4386135059 creator A5083565838 @default.
- W4386135059 date "2023-08-24" @default.
- W4386135059 modified "2023-10-16" @default.
- W4386135059 title "Turning sulfonyl and sulfonimidoyl fluoride electrophiles into sulfur(VI) radicals for alkene ligation" @default.
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