Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386161569> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W4386161569 abstract "A precise and concomitant control of both the size and defects in inorganic materials is of importance in many applications, particularly catalysis, as it often results in enhanced properties or emerging new features. So far, applying the strategy of modulation chemistry has been unable to afford high-quality functional Metal-Organic Frameworks (MOFs) nanocrystals with minimized size while exhibiting maximized defects. We report here a general sustainable strategy for the design of highly defective and ultra-small M(IV)-MOFs crystals (ca. 35% missing linker, 4-6 nm). Advanced characterizations have been performed to shed light on the main factors governing the crystallization mechanism and to identify the nature of the defects. The ultra-small Zr-MOFs showed excellent performance in peptide hydrolysis reaction, including high reactivity, selectivity, diffusion, stability, and show emerging tailorable reactivity and selectivity towards peptide bond formation simply by changing the reaction solvent. Therefore, these highly defective ultra-small tetravalent MOFs particles open new perspectives for the development of heterogeneous MOF catalysts with dual functions." @default.
- W4386161569 created "2023-08-26" @default.
- W4386161569 creator A5003300850 @default.
- W4386161569 creator A5005985227 @default.
- W4386161569 creator A5022764694 @default.
- W4386161569 creator A5027608012 @default.
- W4386161569 creator A5032807322 @default.
- W4386161569 creator A5041025155 @default.
- W4386161569 creator A5046584048 @default.
- W4386161569 date "2023-08-25" @default.
- W4386161569 modified "2023-09-23" @default.
- W4386161569 title "Highly defective ultra-small M(IV)-MOF nanocrystals" @default.
- W4386161569 doi "https://doi.org/10.26434/chemrxiv-2023-q9fd7" @default.
- W4386161569 hasPublicationYear "2023" @default.
- W4386161569 type Work @default.
- W4386161569 citedByCount "0" @default.
- W4386161569 crossrefType "posted-content" @default.
- W4386161569 hasAuthorship W4386161569A5003300850 @default.
- W4386161569 hasAuthorship W4386161569A5005985227 @default.
- W4386161569 hasAuthorship W4386161569A5022764694 @default.
- W4386161569 hasAuthorship W4386161569A5027608012 @default.
- W4386161569 hasAuthorship W4386161569A5032807322 @default.
- W4386161569 hasAuthorship W4386161569A5041025155 @default.
- W4386161569 hasAuthorship W4386161569A5046584048 @default.
- W4386161569 hasBestOaLocation W43861615691 @default.
- W4386161569 hasConcept C111919701 @default.
- W4386161569 hasConcept C118792377 @default.
- W4386161569 hasConcept C121332964 @default.
- W4386161569 hasConcept C127413603 @default.
- W4386161569 hasConcept C142724271 @default.
- W4386161569 hasConcept C150394285 @default.
- W4386161569 hasConcept C161790260 @default.
- W4386161569 hasConcept C171250308 @default.
- W4386161569 hasConcept C175854130 @default.
- W4386161569 hasConcept C178790620 @default.
- W4386161569 hasConcept C179366358 @default.
- W4386161569 hasConcept C185592680 @default.
- W4386161569 hasConcept C192562407 @default.
- W4386161569 hasConcept C203036418 @default.
- W4386161569 hasConcept C204787440 @default.
- W4386161569 hasConcept C21951064 @default.
- W4386161569 hasConcept C2776910235 @default.
- W4386161569 hasConcept C2780471494 @default.
- W4386161569 hasConcept C2780557392 @default.
- W4386161569 hasConcept C41008148 @default.
- W4386161569 hasConcept C42360764 @default.
- W4386161569 hasConcept C69357855 @default.
- W4386161569 hasConcept C71924100 @default.
- W4386161569 hasConcept C97355855 @default.
- W4386161569 hasConceptScore W4386161569C111919701 @default.
- W4386161569 hasConceptScore W4386161569C118792377 @default.
- W4386161569 hasConceptScore W4386161569C121332964 @default.
- W4386161569 hasConceptScore W4386161569C127413603 @default.
- W4386161569 hasConceptScore W4386161569C142724271 @default.
- W4386161569 hasConceptScore W4386161569C150394285 @default.
- W4386161569 hasConceptScore W4386161569C161790260 @default.
- W4386161569 hasConceptScore W4386161569C171250308 @default.
- W4386161569 hasConceptScore W4386161569C175854130 @default.
- W4386161569 hasConceptScore W4386161569C178790620 @default.
- W4386161569 hasConceptScore W4386161569C179366358 @default.
- W4386161569 hasConceptScore W4386161569C185592680 @default.
- W4386161569 hasConceptScore W4386161569C192562407 @default.
- W4386161569 hasConceptScore W4386161569C203036418 @default.
- W4386161569 hasConceptScore W4386161569C204787440 @default.
- W4386161569 hasConceptScore W4386161569C21951064 @default.
- W4386161569 hasConceptScore W4386161569C2776910235 @default.
- W4386161569 hasConceptScore W4386161569C2780471494 @default.
- W4386161569 hasConceptScore W4386161569C2780557392 @default.
- W4386161569 hasConceptScore W4386161569C41008148 @default.
- W4386161569 hasConceptScore W4386161569C42360764 @default.
- W4386161569 hasConceptScore W4386161569C69357855 @default.
- W4386161569 hasConceptScore W4386161569C71924100 @default.
- W4386161569 hasConceptScore W4386161569C97355855 @default.
- W4386161569 hasLocation W43861615691 @default.
- W4386161569 hasOpenAccess W4386161569 @default.
- W4386161569 hasPrimaryLocation W43861615691 @default.
- W4386161569 hasRelatedWork W1976696334 @default.
- W4386161569 hasRelatedWork W1994604850 @default.
- W4386161569 hasRelatedWork W2043405290 @default.
- W4386161569 hasRelatedWork W2085479762 @default.
- W4386161569 hasRelatedWork W2332266322 @default.
- W4386161569 hasRelatedWork W2349556690 @default.
- W4386161569 hasRelatedWork W2376448455 @default.
- W4386161569 hasRelatedWork W2801248804 @default.
- W4386161569 hasRelatedWork W4283814514 @default.
- W4386161569 hasRelatedWork W4318825834 @default.
- W4386161569 isParatext "false" @default.
- W4386161569 isRetracted "false" @default.
- W4386161569 workType "article" @default.