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- W4386204352 endingPage "108980" @default.
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- W4386204352 abstract "Borylation of 1,3-enynes with bis(boronate) compounds often ends up with the formation of hydroborylated products, leaving the diborylation of 1,3-enynes for the formation of 1,4-diborylated allenes to be challenging. Herein, a copper-catalyzed chemo-, regio-, and stereo-selective diborylation of 1,3-enynes for the efficient construction of 1,4-diborylated allenes under base-free conditions was reported. A wide range of 1,3-enynes bearing various functional groups can participant in the reaction and afforded the corresponding 1,4-diborylated allenes in good to excellent yields, which was enabled by the protocol of Bpin to BF3K conversion. the borylcopper species was supposed to selectively attack the C−C triple bond of the 1,3-enynes." @default.
- W4386204352 created "2023-08-28" @default.
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- W4386204352 date "2023-08-01" @default.
- W4386204352 modified "2023-09-24" @default.
- W4386204352 title "Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes" @default.
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- W4386204352 doi "https://doi.org/10.1016/j.cclet.2023.108980" @default.
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