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- W4386209097 abstract "The synthesis of phosphines with light controlled basicity is presented in this study. A methodological approach for the preparation of these unconventional photochromic phosphines based on a dithienylethene organic moiety is reported. It relies on the palladium‐catalyzed annulation of alkynyl phosphines in the presence of a 2,3‐Dithienylsilacyclopropene. Accordingly, a diphenyphosphino moiety is connected to the organic photochrome thanks to different linkers. Their influence on the photochromism and on the phosphinyl group basicity is studied and evaluated based on experimental an NMR descriptor as well as DFT calculations." @default.
- W4386209097 created "2023-08-29" @default.
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- W4386209097 date "2023-08-28" @default.
- W4386209097 modified "2023-10-13" @default.
- W4386209097 title "Synthesis of Photochromic Phosphines by Pd‐Catalyzed Annulation Reaction of Alkynes bearing Phosphinyl Substituent with a Silacyclopropene" @default.
- W4386209097 doi "https://doi.org/10.1002/chem.202302374" @default.
- W4386209097 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37639287" @default.
- W4386209097 hasPublicationYear "2023" @default.
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