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- W4386256598 abstract "Optical anisotropy is pivotal for optical crystals, and it can be characterized by the maximum algebraic difference in refractive indices. Improving the optical anisotropy, especially for deep-ultraviolet (UV) crystals, is still a challenge and of interest. Herein, a new hydroxyfluorooxoborate, Rb[B3O3F2(OH)2], was obtained by the heterologous isomorphic substitution strategy. Dual enhancement for the band gap and birefringence compared with the parent A[B3O3F2(OH)2] (A = [Ph4P]/[Ph3MeP]) compounds was achieved in Rb[B3O3F2(OH)2]. This considerable enhancement originates from the removal of organic components and the retention of a birefringence-active anionic framework. This enhancement pushes the application region from UV to deep-UV. This discovery not only expands the structural chemistry of borates but also demonstrates the viability of heterologous isomorphic substitution to design deep-UV crystals with enhanced optical property." @default.
- W4386256598 created "2023-08-30" @default.
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- W4386256598 date "2023-08-29" @default.
- W4386256598 modified "2023-10-17" @default.
- W4386256598 title "Heterologous Isomorphic Substitution Induces Optical Property Enhancement for Deep-UV Crystals: a Case in Rb[B<sub>3</sub>O<sub>3</sub>F<sub>2</sub>(OH)<sub>2</sub>]" @default.
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- W4386256598 doi "https://doi.org/10.1021/acs.inorgchem.3c02644" @default.
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- W4386256598 hasPublicationYear "2023" @default.
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