Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386274844> ?p ?o ?g. }
- W4386274844 endingPage "12977" @default.
- W4386274844 startingPage "12971" @default.
- W4386274844 abstract "This contribution describes the synthesis of [2.2](1,5)naphthalenoparacyclophane-1,13-diene in four steps from 1,5-bis(bromomethyl)naphthalene and 1,4-benzenedimethanethiol. Consisting of 2,6-dioctyloxynaphthalene and benzene moieties, the effects of differing arene size on the structure, strain energy, and chemical reactivity of the cyclophanediene are examined. Despite a strain energy of 24.3 kcal/mol, the naphthalenoparacyclophanediene was unreactive toward a library of olefin metathesis catalysts. This diminished reactivity can be explained by the steric hindrance of the twisted olefin. Incorporation of an electron donor (naphthalene) into the rigid paracyclophanediene structure can allow for applications in optoelectronics, chiral ligands, and planar chiral materials." @default.
- W4386274844 created "2023-08-31" @default.
- W4386274844 creator A5003353918 @default.
- W4386274844 creator A5054614556 @default.
- W4386274844 creator A5069576120 @default.
- W4386274844 creator A5089582383 @default.
- W4386274844 creator A5092716386 @default.
- W4386274844 date "2023-08-30" @default.
- W4386274844 modified "2023-09-27" @default.
- W4386274844 title "Bent and Twisted: Synthesis of an Alkoxy-Substituted (1,5)Naphthalene-paracyclophanediene" @default.
- W4386274844 cites W1825591757 @default.
- W4386274844 cites W1967836401 @default.
- W4386274844 cites W1970126581 @default.
- W4386274844 cites W1972405488 @default.
- W4386274844 cites W1975002379 @default.
- W4386274844 cites W1976870731 @default.
- W4386274844 cites W1989907469 @default.
- W4386274844 cites W1991666634 @default.
- W4386274844 cites W1992137729 @default.
- W4386274844 cites W2004911209 @default.
- W4386274844 cites W2005076025 @default.
- W4386274844 cites W2009381692 @default.
- W4386274844 cites W2028891075 @default.
- W4386274844 cites W2036274207 @default.
- W4386274844 cites W2038006384 @default.
- W4386274844 cites W2058566203 @default.
- W4386274844 cites W2059581905 @default.
- W4386274844 cites W2086377934 @default.
- W4386274844 cites W2092008537 @default.
- W4386274844 cites W2171559455 @default.
- W4386274844 cites W2262346995 @default.
- W4386274844 cites W2320978761 @default.
- W4386274844 cites W2329671146 @default.
- W4386274844 cites W2333533899 @default.
- W4386274844 cites W2414635203 @default.
- W4386274844 cites W2494215589 @default.
- W4386274844 cites W2584486239 @default.
- W4386274844 cites W2747212214 @default.
- W4386274844 cites W2757968152 @default.
- W4386274844 cites W2765500293 @default.
- W4386274844 cites W2885951693 @default.
- W4386274844 cites W2949862345 @default.
- W4386274844 cites W2952104658 @default.
- W4386274844 cites W2956618409 @default.
- W4386274844 cites W3037280006 @default.
- W4386274844 cites W3084048146 @default.
- W4386274844 cites W3174703477 @default.
- W4386274844 cites W3196148891 @default.
- W4386274844 cites W3205205220 @default.
- W4386274844 cites W3212341350 @default.
- W4386274844 cites W4200594282 @default.
- W4386274844 cites W4223449233 @default.
- W4386274844 cites W4230549224 @default.
- W4386274844 cites W4238267547 @default.
- W4386274844 cites W4239599500 @default.
- W4386274844 cites W4290879891 @default.
- W4386274844 cites W4310080447 @default.
- W4386274844 doi "https://doi.org/10.1021/acs.joc.3c00880" @default.
- W4386274844 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37647456" @default.
- W4386274844 hasPublicationYear "2023" @default.
- W4386274844 type Work @default.
- W4386274844 citedByCount "0" @default.
- W4386274844 crossrefType "journal-article" @default.
- W4386274844 hasAuthorship W4386274844A5003353918 @default.
- W4386274844 hasAuthorship W4386274844A5054614556 @default.
- W4386274844 hasAuthorship W4386274844A5069576120 @default.
- W4386274844 hasAuthorship W4386274844A5089582383 @default.
- W4386274844 hasAuthorship W4386274844A5092716386 @default.
- W4386274844 hasBestOaLocation W43862748441 @default.
- W4386274844 hasConcept C107111320 @default.
- W4386274844 hasConcept C138211643 @default.
- W4386274844 hasConcept C142724271 @default.
- W4386274844 hasConcept C153914509 @default.
- W4386274844 hasConcept C155647269 @default.
- W4386274844 hasConcept C161790260 @default.
- W4386274844 hasConcept C176933379 @default.
- W4386274844 hasConcept C178790620 @default.
- W4386274844 hasConcept C185592680 @default.
- W4386274844 hasConcept C201194858 @default.
- W4386274844 hasConcept C204787440 @default.
- W4386274844 hasConcept C2776910235 @default.
- W4386274844 hasConcept C2777691172 @default.
- W4386274844 hasConcept C2778733088 @default.
- W4386274844 hasConcept C2779255514 @default.
- W4386274844 hasConcept C2780263894 @default.
- W4386274844 hasConcept C2994504213 @default.
- W4386274844 hasConcept C32909587 @default.
- W4386274844 hasConcept C44228677 @default.
- W4386274844 hasConcept C51886252 @default.
- W4386274844 hasConcept C521977710 @default.
- W4386274844 hasConcept C71240020 @default.
- W4386274844 hasConcept C71924100 @default.
- W4386274844 hasConcept C90150868 @default.
- W4386274844 hasConceptScore W4386274844C107111320 @default.
- W4386274844 hasConceptScore W4386274844C138211643 @default.
- W4386274844 hasConceptScore W4386274844C142724271 @default.
- W4386274844 hasConceptScore W4386274844C153914509 @default.
- W4386274844 hasConceptScore W4386274844C155647269 @default.