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- W4386282906 abstract "Abstract The catalytic activity of multifunctional, microporous materials is directly linked to the spatial arrangement of their structural building blocks. Despite great achievements in the design and incorporation of isolated catalytically active metal complexes within such materials, a detailed understanding of their atomic‐level structure and the local environment of the active species remains a fundamental challenge, especially when these latter are hosted in non‐crystalline organic polymers. Here, we show that by combining computational chemistry with pair distribution function analysis, 129 Xe NMR, and Dynamic Nuclear Polarization enhanced NMR spectroscopy, a very accurate description of the molecular structure and confining surroundings of a catalytically active Rh‐based organometallic complex incorporated inside the cavity of amorphous bipyridine‐based porous polymers is obtained. Small, but significant, differences in the structural properties of the polymers are highlighted depending on their backbone motifs." @default.
- W4386282906 created "2023-08-31" @default.
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- W4386282906 date "2023-09-26" @default.
- W4386282906 modified "2023-10-16" @default.
- W4386282906 title "Unravelling the Molecular Structure and Confining Environment of an Organometallic Catalyst Heterogenized within Amorphous Porous Polymers" @default.
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- W4386282906 doi "https://doi.org/10.1002/anie.202310878" @default.
- W4386282906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37647152" @default.
- W4386282906 hasPublicationYear "2023" @default.
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