Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386288933> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W4386288933 abstract "Triptycene derivatives are used extensively in supramolecular and materials chemistry, however, most are prepared using a multi-step synthesis that involves the generation of a benzyne intermediate, which hinders scale-up. Inspired by the ease of resorcinarene synthesis, we report the rapid and efficient preparation of triptycene-like 1,6,2’,7’-tetrahydroxynaphthopleiadene directly from 2,7-dihydroxynaphthalene and phthalaldehyde. Structural characterisation confirms the novel bridged bicyclic framework, within which the planes of the single benzene ring and two naphthalene units are fixed at an angle of ~120° relative to each other. Several simple variations of aromatic 1,2-dialdehydes and 2,7-disubstituted naphthalenes also provided triptycene-like products. The low cost of the precursors and undemanding reaction conditions allows for rapid multigram synthesis of 1,6,2’,7’-tetrahydroxynaphthopleiadene with product isolation by simple filtration. The potential for its use in supramolecular and polymer chemistry was demonstrated by the preparation of a very rigid novel cavitand, a microporous network polymer, and a solution-processable polymer of Intrinsic microporosity." @default.
- W4386288933 created "2023-08-31" @default.
- W4386288933 creator A5011880520 @default.
- W4386288933 creator A5021598710 @default.
- W4386288933 creator A5026220204 @default.
- W4386288933 creator A5039030011 @default.
- W4386288933 creator A5054940417 @default.
- W4386288933 creator A5070900555 @default.
- W4386288933 date "2023-08-30" @default.
- W4386288933 modified "2023-10-01" @default.
- W4386288933 title "Rapid access to triptycene-like naphthopleiadenes for use in supramolecular and materials chemistry" @default.
- W4386288933 doi "https://doi.org/10.26434/chemrxiv-2023-k1r08" @default.
- W4386288933 hasPublicationYear "2023" @default.
- W4386288933 type Work @default.
- W4386288933 citedByCount "0" @default.
- W4386288933 crossrefType "posted-content" @default.
- W4386288933 hasAuthorship W4386288933A5011880520 @default.
- W4386288933 hasAuthorship W4386288933A5021598710 @default.
- W4386288933 hasAuthorship W4386288933A5026220204 @default.
- W4386288933 hasAuthorship W4386288933A5039030011 @default.
- W4386288933 hasAuthorship W4386288933A5054940417 @default.
- W4386288933 hasAuthorship W4386288933A5070900555 @default.
- W4386288933 hasBestOaLocation W43862889331 @default.
- W4386288933 hasConcept C115624301 @default.
- W4386288933 hasConcept C163893822 @default.
- W4386288933 hasConcept C171250308 @default.
- W4386288933 hasConcept C171811041 @default.
- W4386288933 hasConcept C178790620 @default.
- W4386288933 hasConcept C185592680 @default.
- W4386288933 hasConcept C188027245 @default.
- W4386288933 hasConcept C192562407 @default.
- W4386288933 hasConcept C21951064 @default.
- W4386288933 hasConcept C2775991357 @default.
- W4386288933 hasConcept C2780016452 @default.
- W4386288933 hasConcept C32909587 @default.
- W4386288933 hasConcept C86381522 @default.
- W4386288933 hasConcept C93275456 @default.
- W4386288933 hasConceptScore W4386288933C115624301 @default.
- W4386288933 hasConceptScore W4386288933C163893822 @default.
- W4386288933 hasConceptScore W4386288933C171250308 @default.
- W4386288933 hasConceptScore W4386288933C171811041 @default.
- W4386288933 hasConceptScore W4386288933C178790620 @default.
- W4386288933 hasConceptScore W4386288933C185592680 @default.
- W4386288933 hasConceptScore W4386288933C188027245 @default.
- W4386288933 hasConceptScore W4386288933C192562407 @default.
- W4386288933 hasConceptScore W4386288933C21951064 @default.
- W4386288933 hasConceptScore W4386288933C2775991357 @default.
- W4386288933 hasConceptScore W4386288933C2780016452 @default.
- W4386288933 hasConceptScore W4386288933C32909587 @default.
- W4386288933 hasConceptScore W4386288933C86381522 @default.
- W4386288933 hasConceptScore W4386288933C93275456 @default.
- W4386288933 hasFunder F4320334627 @default.
- W4386288933 hasLocation W43862889331 @default.
- W4386288933 hasOpenAccess W4386288933 @default.
- W4386288933 hasPrimaryLocation W43862889331 @default.
- W4386288933 hasRelatedWork W2053049024 @default.
- W4386288933 hasRelatedWork W2056813012 @default.
- W4386288933 hasRelatedWork W2460217897 @default.
- W4386288933 hasRelatedWork W2558066155 @default.
- W4386288933 hasRelatedWork W2952544533 @default.
- W4386288933 hasRelatedWork W3004882533 @default.
- W4386288933 hasRelatedWork W3081400920 @default.
- W4386288933 hasRelatedWork W3210807071 @default.
- W4386288933 hasRelatedWork W4385623174 @default.
- W4386288933 hasRelatedWork W4386288933 @default.
- W4386288933 isParatext "false" @default.
- W4386288933 isRetracted "false" @default.
- W4386288933 workType "article" @default.