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- W4386364223 abstract "Chemists and chemical engineers from the University of Wisconsin–Madison and Merck & Co. have devised an effective and scalable way to use hydrogen’s electrons in an electrochemical reduction reaction under water-free conditions ( Nature 2023, DOI: 10.1038/s41586-023-06534-2 ). Conventional reductions use metals such as zinc, manganese, and magnesium as sacrificial electron sources. Merck and other companies are interested in finding ways to drive organic reactions with electrochemistry, but “they weren’t excited about making equimolar amounts of zinc salts,” says Daniel Weix , a UW chemistry professor who lent his expertise in cross-electrophile couplings to the project . Enter hydrogen. H 2 is increasingly made using renewable energy , and taking its two electrons leaves two protons, which like to join up with oxygen atoms to make water. “It’s tough to find a reductant that’s greener than hydrogen,” says UW’s Shannon Stahl , who led the collaboration. He and his colleagues" @default.
- W4386364223 created "2023-09-02" @default.
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- W4386364223 date "2023-09-04" @default.
- W4386364223 modified "2023-09-28" @default.
- W4386364223 title "Charging up H<sub>2</sub> as a greener reductant" @default.
- W4386364223 doi "https://doi.org/10.1021/cen-10129-scicon1" @default.
- W4386364223 hasPublicationYear "2023" @default.
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