Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386406989> ?p ?o ?g. }
- W4386406989 endingPage "19911" @default.
- W4386406989 startingPage "19903" @default.
- W4386406989 abstract "Removal of the CO2 impurities from C2H2/CO2 mixtures is an essential process to produce high-purity C2H2. Fabricating an adsorbent capable of discriminating these species, which have close kinetic diameters, is critical for developing advanced adsorption processes. Herein, we demonstrate a strategy to exploit the tunability of interlayer and intralayer spaces of two-dimensional (2D) layered metal–organic frameworks to achieve high performance for C2H2/CO2 separation. This indicates that interlayer symmetrical control can achieve more efficient packing of C2H2 into Ni(4-DPDS)2CrO4, with a high C2H2 capacity of 45.7 cm3·g–1 at 0.01 bar and a selectivity of 67.7 (298 K, 1 bar), which strikes a good balance between working capacity and separation selectivity compared to other isostructural Ni(4-DPDS)2MO4 (M = Mo, W). Crystallographic studies and DFT-D calculations reveal that such a C2H2-selective adsorbent possesses strong binding interactions due to the tailored pore confinement provided by the angular anions and rich electronic environment. Experimental breakthrough results comprehensively demonstrate the efficient C2H2/CO2 separation performance of this unique material." @default.
- W4386406989 created "2023-09-05" @default.
- W4386406989 creator A5001235693 @default.
- W4386406989 creator A5013322053 @default.
- W4386406989 creator A5035908118 @default.
- W4386406989 creator A5051131549 @default.
- W4386406989 creator A5060002817 @default.
- W4386406989 creator A5069311994 @default.
- W4386406989 creator A5081019345 @default.
- W4386406989 creator A5086923958 @default.
- W4386406989 creator A5091691715 @default.
- W4386406989 date "2023-09-04" @default.
- W4386406989 modified "2023-10-14" @default.
- W4386406989 title "Interlayer Symmetry Control in Flexible-Robust Layered Metal–Organic Frameworks for Highly Efficient C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation" @default.
- W4386406989 cites W1977469333 @default.
- W4386406989 cites W1987769154 @default.
- W4386406989 cites W2021104294 @default.
- W4386406989 cites W2074675175 @default.
- W4386406989 cites W2099486431 @default.
- W4386406989 cites W2107991409 @default.
- W4386406989 cites W2127106839 @default.
- W4386406989 cites W2402426102 @default.
- W4386406989 cites W2550243666 @default.
- W4386406989 cites W2580793391 @default.
- W4386406989 cites W2621160901 @default.
- W4386406989 cites W2762380112 @default.
- W4386406989 cites W2768020335 @default.
- W4386406989 cites W2768187522 @default.
- W4386406989 cites W2769954071 @default.
- W4386406989 cites W2770720622 @default.
- W4386406989 cites W2803066542 @default.
- W4386406989 cites W2810186787 @default.
- W4386406989 cites W2915735482 @default.
- W4386406989 cites W2951734841 @default.
- W4386406989 cites W2951837007 @default.
- W4386406989 cites W2967396522 @default.
- W4386406989 cites W2977857051 @default.
- W4386406989 cites W2982056413 @default.
- W4386406989 cites W2998819515 @default.
- W4386406989 cites W3023308961 @default.
- W4386406989 cites W3094120041 @default.
- W4386406989 cites W3094674842 @default.
- W4386406989 cites W3110895353 @default.
- W4386406989 cites W3118581976 @default.
- W4386406989 cites W3118847022 @default.
- W4386406989 cites W3137789272 @default.
- W4386406989 cites W3160532116 @default.
- W4386406989 cites W3181037326 @default.
- W4386406989 cites W3190678253 @default.
- W4386406989 cites W3192216667 @default.
- W4386406989 cites W3198932750 @default.
- W4386406989 cites W4206292303 @default.
- W4386406989 cites W4206400878 @default.
- W4386406989 cites W584377838 @default.
- W4386406989 cites W613351740 @default.
- W4386406989 doi "https://doi.org/10.1021/jacs.3c06138" @default.
- W4386406989 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37661421" @default.
- W4386406989 hasPublicationYear "2023" @default.
- W4386406989 type Work @default.
- W4386406989 citedByCount "0" @default.
- W4386406989 crossrefType "journal-article" @default.
- W4386406989 hasAuthorship W4386406989A5001235693 @default.
- W4386406989 hasAuthorship W4386406989A5013322053 @default.
- W4386406989 hasAuthorship W4386406989A5035908118 @default.
- W4386406989 hasAuthorship W4386406989A5051131549 @default.
- W4386406989 hasAuthorship W4386406989A5060002817 @default.
- W4386406989 hasAuthorship W4386406989A5069311994 @default.
- W4386406989 hasAuthorship W4386406989A5081019345 @default.
- W4386406989 hasAuthorship W4386406989A5086923958 @default.
- W4386406989 hasAuthorship W4386406989A5091691715 @default.
- W4386406989 hasConcept C115624301 @default.
- W4386406989 hasConcept C118792377 @default.
- W4386406989 hasConcept C121332964 @default.
- W4386406989 hasConcept C127413603 @default.
- W4386406989 hasConcept C147789679 @default.
- W4386406989 hasConcept C150394285 @default.
- W4386406989 hasConcept C153294291 @default.
- W4386406989 hasConcept C161790260 @default.
- W4386406989 hasConcept C178790620 @default.
- W4386406989 hasConcept C179366358 @default.
- W4386406989 hasConcept C185592680 @default.
- W4386406989 hasConcept C188721877 @default.
- W4386406989 hasConcept C205188671 @default.
- W4386406989 hasConcept C2991957519 @default.
- W4386406989 hasConcept C42360764 @default.
- W4386406989 hasConcept C544153396 @default.
- W4386406989 hasConcept C71987851 @default.
- W4386406989 hasConcept C8010536 @default.
- W4386406989 hasConceptScore W4386406989C115624301 @default.
- W4386406989 hasConceptScore W4386406989C118792377 @default.
- W4386406989 hasConceptScore W4386406989C121332964 @default.
- W4386406989 hasConceptScore W4386406989C127413603 @default.
- W4386406989 hasConceptScore W4386406989C147789679 @default.
- W4386406989 hasConceptScore W4386406989C150394285 @default.
- W4386406989 hasConceptScore W4386406989C153294291 @default.
- W4386406989 hasConceptScore W4386406989C161790260 @default.
- W4386406989 hasConceptScore W4386406989C178790620 @default.
- W4386406989 hasConceptScore W4386406989C179366358 @default.