Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386420932> ?p ?o ?g. }
- W4386420932 abstract "Metal exsolution engineering has been regarded as a promising strategy for activating intrinsically inert perovskite oxide catalysts toward efficient oxygen evolution reaction. Traditional metal exsolution processes on perovskites are often achieved by using the reducing hydrogen gas; however, this is not effective for the relatively stable phase, such as Ruddlesden–Popper perovskite oxides. To address this issue, triphenylphosphine is proposed to be a reduction promotor for accelerating the reduction and migration of the target metal atoms, aiming to achieve the effective exsolution of metallic species from Ruddlesden–Popper‐type parent perovskites. Upon oxygen evolution reaction, these exsolved metallic aggregates are reconstructed into oxyhydroxides as the real active centers. After further modification by low‐percentage iridium oxide nanoclusters, the optimal catalyst delivered an overpotential as low as 305 mV for generating the density of 10 mA cm −2 , outperforming these reported noble metal‐containing perovskite‐based alkaline oxygen evolution reaction electrocatalysts. This work provides a potential approach to activate catalytically inert oxides through promoting surface metal exsolution and explores a novel class of Ruddlesden–Popper‐type oxides for electrocatalytic applications." @default.
- W4386420932 created "2023-09-05" @default.
- W4386420932 creator A5003339166 @default.
- W4386420932 creator A5016086224 @default.
- W4386420932 creator A5021729737 @default.
- W4386420932 creator A5023347434 @default.
- W4386420932 creator A5029410439 @default.
- W4386420932 creator A5036383130 @default.
- W4386420932 date "2023-09-04" @default.
- W4386420932 modified "2023-10-15" @default.
- W4386420932 title "Triphenylphosphine‐Assisted Exsolution Engineering on Ruddlesden–Popper Perovskites for Promoting Oxygen Evolution" @default.
- W4386420932 cites W1973891115 @default.
- W4386420932 cites W2007978716 @default.
- W4386420932 cites W2076968595 @default.
- W4386420932 cites W2112320230 @default.
- W4386420932 cites W2128689637 @default.
- W4386420932 cites W2131416620 @default.
- W4386420932 cites W2268456782 @default.
- W4386420932 cites W2332664138 @default.
- W4386420932 cites W2403509034 @default.
- W4386420932 cites W2537945104 @default.
- W4386420932 cites W2571310289 @default.
- W4386420932 cites W2574987849 @default.
- W4386420932 cites W2594502222 @default.
- W4386420932 cites W2763025117 @default.
- W4386420932 cites W2769990470 @default.
- W4386420932 cites W2788695181 @default.
- W4386420932 cites W2885055243 @default.
- W4386420932 cites W2886195470 @default.
- W4386420932 cites W2912480276 @default.
- W4386420932 cites W2914215539 @default.
- W4386420932 cites W2914976120 @default.
- W4386420932 cites W2915055812 @default.
- W4386420932 cites W2947317914 @default.
- W4386420932 cites W2954797232 @default.
- W4386420932 cites W2955883988 @default.
- W4386420932 cites W2963672987 @default.
- W4386420932 cites W2986339634 @default.
- W4386420932 cites W2990737434 @default.
- W4386420932 cites W2996027457 @default.
- W4386420932 cites W3006115260 @default.
- W4386420932 cites W3015170447 @default.
- W4386420932 cites W3016261179 @default.
- W4386420932 cites W3016647108 @default.
- W4386420932 cites W3031164653 @default.
- W4386420932 cites W3033175870 @default.
- W4386420932 cites W3086202193 @default.
- W4386420932 cites W3096167015 @default.
- W4386420932 cites W3120690228 @default.
- W4386420932 cites W3126546093 @default.
- W4386420932 cites W3130240373 @default.
- W4386420932 cites W3155718568 @default.
- W4386420932 cites W3159209256 @default.
- W4386420932 cites W3159468613 @default.
- W4386420932 cites W3168963170 @default.
- W4386420932 cites W3184770815 @default.
- W4386420932 cites W3202348700 @default.
- W4386420932 cites W3206915225 @default.
- W4386420932 cites W3213937605 @default.
- W4386420932 cites W3213952360 @default.
- W4386420932 cites W4200118872 @default.
- W4386420932 cites W4200190789 @default.
- W4386420932 cites W4200282282 @default.
- W4386420932 cites W4280645171 @default.
- W4386420932 cites W4281626784 @default.
- W4386420932 cites W4281683898 @default.
- W4386420932 cites W4281770237 @default.
- W4386420932 cites W4281789781 @default.
- W4386420932 cites W4281992597 @default.
- W4386420932 cites W4282570260 @default.
- W4386420932 cites W4283030766 @default.
- W4386420932 cites W4290652627 @default.
- W4386420932 cites W4376112828 @default.
- W4386420932 cites W4378417236 @default.
- W4386420932 doi "https://doi.org/10.1002/eem2.12668" @default.
- W4386420932 hasPublicationYear "2023" @default.
- W4386420932 type Work @default.
- W4386420932 citedByCount "0" @default.
- W4386420932 crossrefType "journal-article" @default.
- W4386420932 hasAuthorship W4386420932A5003339166 @default.
- W4386420932 hasAuthorship W4386420932A5016086224 @default.
- W4386420932 hasAuthorship W4386420932A5021729737 @default.
- W4386420932 hasAuthorship W4386420932A5023347434 @default.
- W4386420932 hasAuthorship W4386420932A5029410439 @default.
- W4386420932 hasAuthorship W4386420932A5036383130 @default.
- W4386420932 hasBestOaLocation W43864209321 @default.
- W4386420932 hasConcept C127413603 @default.
- W4386420932 hasConcept C135473242 @default.
- W4386420932 hasConcept C147789679 @default.
- W4386420932 hasConcept C155011858 @default.
- W4386420932 hasConcept C161790260 @default.
- W4386420932 hasConcept C171250308 @default.
- W4386420932 hasConcept C17525397 @default.
- W4386420932 hasConcept C178790620 @default.
- W4386420932 hasConcept C179104552 @default.
- W4386420932 hasConcept C185592680 @default.
- W4386420932 hasConcept C186460083 @default.
- W4386420932 hasConcept C191897082 @default.
- W4386420932 hasConcept C192562407 @default.
- W4386420932 hasConcept C2775871042 @default.