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- W4386424905 abstract "The evolution of electronic communication technology raises higher requirements for low dielectric constant (low-k) materials. For this, a benzoxazine functional organosilicon (HP-aptes) with dense Si—O—Si crosslinking networks and large sterically hindered tert-butyl groups was prepared by the sol-gel method. Then, a series of polybenzoxazine composites (PPHP) were prepared from intrinsically low dielectric constant bis-functional benzoxazine monomer (P-aptmds) and HP-aptes. The double crosslinking networks of polybenzoxazine and organosilicon further increased the crosslinking density and decreased the dipole density of composites, which endowed the composites with enhanced low-k properties. When the content of HP-aptes is 30% (mass), the crosslinking density was 2.05×10−3 mol·cm−3, while that of PP-aptmds was 3.31×10−3 mol·cm−3. In addition, the dielectric constant and dielectric loss of PPHP composite at 1 MHz could reach 2.61 and 0.0056, respectively." @default.
- W4386424905 created "2023-09-05" @default.
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- W4386424905 date "2023-09-01" @default.
- W4386424905 modified "2023-09-27" @default.
- W4386424905 title "Polybenzoxazine/organosilicon composites with low dielectric constant and dielectric loss" @default.
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- W4386424905 doi "https://doi.org/10.1016/j.cjche.2023.06.024" @default.
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