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• W4386447518 abstract "A carbonylation-carboxylation synthetic sequence, via double CO2 fixation, is described. The productive merger of a Ni-catalyzed cross-electrophile coupling manifold, with the use of AlCl3, triggered a cascade reaction with the formation of three consecutive C-C bonds in a single operation. This strategy traces an unprecedented synthetic route to ketones under Lewis acid assisted carbon dioxide valorization. Computational insights revealed a unique double function of AlCl3, and labeling (13CO2) experiments validate the genuine incorporation of CO2 in both functional groups." @default.
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• W4386447518 date "2023-09-05" @default.
• W4386447518 modified "2023-10-01" @default.
• W4386447518 title "Nickel Catalyzed Carbonylation/Carboxylation Sequence via Double CO₂ Incorporation" @default.
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• W4386447518 doi "https://doi.org/10.1021/acs.orglett.3c02394" @default.
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