Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386449705> ?p ?o ?g. }
- W4386449705 abstract "Hydrogel electrolytes hold great promise in developing flexible and safe batteries, but the presence of free solvent water makes battery chemistries constrained by H2 evolution and electrode dissolution. Although maximizing salt concentration is recognized as an effective strategy to reduce water activity, the protic polymer matrices in classical hydrogels are occupied with hydrogen-bonding and barely involved in the salt dissolution, which sets limitations on realizing stable salt-concentrated environments before polymer-salt phase separation occurs. Inspired by the role of protein methylation in regulating intracellular phase separation, here we transform the inert protic polymer skeletons into aprotic ones through methylation modification to weaken the hydrogen-bonding, which releases free hydrogen bond acceptors as Lewis base sites to participate in cation solvation and thus assist salt dissolution. An unconventionally salt-concentrated hydrogel electrolyte reaching a salt fraction up to 44 mol % while retaining a high Na+ /H2 O molar ratio of 1.0 is achieved without phase separation. Almost all water molecules are confined in the solvation shell of Na+ with depressed activity and mobility, which addresses water-induced parasitic reactions that limit the practical rechargeability of aqueous sodium-ion batteries. The assembled Na3 V2 (PO4 )3 //NaTi2 (PO4 )3 cell maintains 82.8 % capacity after 580 cycles, which is the longest cycle life reported to date." @default.
- W4386449705 created "2023-09-06" @default.
- W4386449705 creator A5006309785 @default.
- W4386449705 creator A5019749834 @default.
- W4386449705 creator A5032769690 @default.
- W4386449705 creator A5041920497 @default.
- W4386449705 creator A5053272104 @default.
- W4386449705 creator A5068115518 @default.
- W4386449705 creator A5076863688 @default.
- W4386449705 creator A5079176132 @default.
- W4386449705 creator A5080102032 @default.
- W4386449705 date "2023-09-18" @default.
- W4386449705 modified "2023-10-18" @default.
- W4386449705 title "A Bio‐Inspired Methylation Approach to Salt‐Concentrated Hydrogel Electrolytes for Long‐Life Rechargeable Batteries" @default.
- W4386449705 cites W1576668315 @default.
- W4386449705 cites W1986634012 @default.
- W4386449705 cites W1988752021 @default.
- W4386449705 cites W1995013799 @default.
- W4386449705 cites W2000375978 @default.
- W4386449705 cites W2009824659 @default.
- W4386449705 cites W2031920731 @default.
- W4386449705 cites W2058599209 @default.
- W4386449705 cites W2059838064 @default.
- W4386449705 cites W2074411536 @default.
- W4386449705 cites W2097163271 @default.
- W4386449705 cites W2129122149 @default.
- W4386449705 cites W2229124923 @default.
- W4386449705 cites W2327960820 @default.
- W4386449705 cites W2342481369 @default.
- W4386449705 cites W2484748049 @default.
- W4386449705 cites W2510164568 @default.
- W4386449705 cites W2537214968 @default.
- W4386449705 cites W2567282396 @default.
- W4386449705 cites W2738732016 @default.
- W4386449705 cites W2745098610 @default.
- W4386449705 cites W2775324813 @default.
- W4386449705 cites W2783363964 @default.
- W4386449705 cites W2789332115 @default.
- W4386449705 cites W2794654572 @default.
- W4386449705 cites W2800104465 @default.
- W4386449705 cites W2800441358 @default.
- W4386449705 cites W2801688422 @default.
- W4386449705 cites W2802667264 @default.
- W4386449705 cites W2802884330 @default.
- W4386449705 cites W2809746634 @default.
- W4386449705 cites W2891072321 @default.
- W4386449705 cites W2896078086 @default.
- W4386449705 cites W2898155559 @default.
- W4386449705 cites W2903669982 @default.
- W4386449705 cites W2906593639 @default.
- W4386449705 cites W2913509851 @default.
- W4386449705 cites W2921649589 @default.
- W4386449705 cites W2946001856 @default.
- W4386449705 cites W2965363371 @default.
- W4386449705 cites W2988330985 @default.
- W4386449705 cites W2989638000 @default.
- W4386449705 cites W2991346024 @default.
- W4386449705 cites W2997842093 @default.
- W4386449705 cites W3007350830 @default.
- W4386449705 cites W3011973437 @default.
- W4386449705 cites W3016760662 @default.
- W4386449705 cites W3026311113 @default.
- W4386449705 cites W3046720988 @default.
- W4386449705 cites W3047827930 @default.
- W4386449705 cites W3086488624 @default.
- W4386449705 cites W3091751712 @default.
- W4386449705 cites W3111232582 @default.
- W4386449705 cites W3133587928 @default.
- W4386449705 cites W3164763598 @default.
- W4386449705 cites W3173072585 @default.
- W4386449705 cites W3175103029 @default.
- W4386449705 cites W3186773808 @default.
- W4386449705 cites W4206371874 @default.
- W4386449705 cites W4221005897 @default.
- W4386449705 cites W4284988155 @default.
- W4386449705 cites W4285728421 @default.
- W4386449705 cites W4295366659 @default.
- W4386449705 cites W4309683980 @default.
- W4386449705 cites W4322581107 @default.
- W4386449705 doi "https://doi.org/10.1002/anie.202311589" @default.
- W4386449705 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37669903" @default.
- W4386449705 hasPublicationYear "2023" @default.
- W4386449705 type Work @default.
- W4386449705 citedByCount "0" @default.
- W4386449705 crossrefType "journal-article" @default.
- W4386449705 hasAuthorship W4386449705A5006309785 @default.
- W4386449705 hasAuthorship W4386449705A5019749834 @default.
- W4386449705 hasAuthorship W4386449705A5032769690 @default.
- W4386449705 hasAuthorship W4386449705A5041920497 @default.
- W4386449705 hasAuthorship W4386449705A5053272104 @default.
- W4386449705 hasAuthorship W4386449705A5068115518 @default.
- W4386449705 hasAuthorship W4386449705A5076863688 @default.
- W4386449705 hasAuthorship W4386449705A5079176132 @default.
- W4386449705 hasAuthorship W4386449705A5080102032 @default.
- W4386449705 hasConcept C112887158 @default.
- W4386449705 hasConcept C127413603 @default.
- W4386449705 hasConcept C147789679 @default.
- W4386449705 hasConcept C148093993 @default.
- W4386449705 hasConcept C17525397 @default.
- W4386449705 hasConcept C178790620 @default.