FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386458464> ?p ?o ?g. }

• W4386458464 abstract "Abstract. The apparent volatility of atmospheric organic aerosol (OA) particles is determined by their chemical composition and environmental conditions (e.g., ambient temperature). A quantitative, experimental assessment of volatility and the respective importance of these two factors remains challenging, especially in ambient measurements. We present molecular composition and volatility of oxygenated OA (OOA) particles in different rural, urban, and remote environments across the globe (including Chacaltaya, Bolivia; Alabama, U.S.; Hyytiälä, Finland; Stuttgart and Karlsruhe, Germany; and Delhi, India) based on deployments of a filter inlet for gases and aerosols coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (FIGAERO-CIMS). We find on average larger carbon numbers (nC) and lower oxygen-to-carbon (O:C) ratios at the urban sites (nC: 9.8±0.7; O:C: 0.76±0.03; average ± 1 standard deviation), compared to the rural (nC: 8.8±0.6; O:C: 0.80±0.05) and remote mountain stations (nC: 8.1±0.8; O:C: 0.91±0.07), indicative of different emission sources and chemistry. Compounds containing only carbon, hydrogen, and oxygen atoms (CHO) contribute highest to the total OOA mass at the rural sites (79.9±5.2 %), in accordance with their proximity to forested areas (66.2±5.5 % at the mountain sites and 72.6±4.3 % at the urban sites). The largest contribution of nitrogen-containing compounds (CHON) are found at the urban stations (27.1±4.3 %), consistent with their higher NOx levels. Besides, we parametrize OOA volatility (saturation mass concentrations, Csat) using molecular composition information and compare it with the bulk apparent volatility derived from thermal desorption of the OOA particles within the FIGAERO. We find differences in Csat values of up to ~3 orders of magnitude, and variation in thermal desorption profiles (thermograms) across different locations and systems. From our study, we draw the general conclusion that environmental conditions (e.g., ambient temperature) do not directly affect OOA apparent volatility, but rather indirectly by influencing the sources and chemistry of the environment and thus the chemical composition. The comprehensive global dataset provides results that show the complex thermodynamics and chemistry of OOA and their changes during its lifetime in the atmosphere, and that generally the chemical description of OOA suffices to predict its apparent volatility, at least qualitatively. Our study thus provides new insights that will help guide choices of e.g. descriptions of OOA volatility in different model frameworks which has been previously simplified due to challenges to measure and represent it in models." @default.
• W4386458464 created "2023-09-06" @default.
• W4386458464 creator A5007291045 @default.
• W4386458464 creator A5008549381 @default.
• W4386458464 creator A5009421974 @default.
• W4386458464 creator A5012071001 @default.
• W4386458464 creator A5016340715 @default.
• W4386458464 creator A5017872126 @default.
• W4386458464 creator A5021283897 @default.
• W4386458464 creator A5023986463 @default.
• W4386458464 creator A5031442270 @default.
• W4386458464 creator A5031798214 @default.
• W4386458464 creator A5033551265 @default.
• W4386458464 creator A5041978259 @default.
• W4386458464 creator A5046542754 @default.
• W4386458464 creator A5053686310 @default.
• W4386458464 creator A5078365507 @default.
• W4386458464 creator A5078546339 @default.
• W4386458464 creator A5079136519 @default.
• W4386458464 creator A5086642777 @default.
• W4386458464 creator A5090896169 @default.
• W4386458464 date "2023-09-05" @default.
• W4386458464 modified "2023-10-09" @default.
• W4386458464 title "Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and remote environments" @default.
• W4386458464 doi "https://doi.org/10.5194/egusphere-2023-1821" @default.
• W4386458464 hasPublicationYear "2023" @default.
• W4386458464 type Work @default.
• W4386458464 citedByCount "0" @default.
• W4386458464 crossrefType "posted-content" @default.
• W4386458464 hasAuthorship W4386458464A5007291045 @default.
• W4386458464 hasAuthorship W4386458464A5008549381 @default.
• W4386458464 hasAuthorship W4386458464A5009421974 @default.
• W4386458464 hasAuthorship W4386458464A5012071001 @default.
• W4386458464 hasAuthorship W4386458464A5016340715 @default.
• W4386458464 hasAuthorship W4386458464A5017872126 @default.
• W4386458464 hasAuthorship W4386458464A5021283897 @default.
• W4386458464 hasAuthorship W4386458464A5023986463 @default.
• W4386458464 hasAuthorship W4386458464A5031442270 @default.
• W4386458464 hasAuthorship W4386458464A5031798214 @default.
• W4386458464 hasAuthorship W4386458464A5033551265 @default.
• W4386458464 hasAuthorship W4386458464A5041978259 @default.
• W4386458464 hasAuthorship W4386458464A5046542754 @default.
• W4386458464 hasAuthorship W4386458464A5053686310 @default.
• W4386458464 hasAuthorship W4386458464A5078365507 @default.
• W4386458464 hasAuthorship W4386458464A5078546339 @default.
• W4386458464 hasAuthorship W4386458464A5079136519 @default.
• W4386458464 hasAuthorship W4386458464A5086642777 @default.
• W4386458464 hasAuthorship W4386458464A5090896169 @default.
• W4386458464 hasBestOaLocation W43864584641 @default.
• W4386458464 hasConcept C105923489 @default.
• W4386458464 hasConcept C106159729 @default.
• W4386458464 hasConcept C107872376 @default.
• W4386458464 hasConcept C113196181 @default.
• W4386458464 hasConcept C127313418 @default.
• W4386458464 hasConcept C149849071 @default.
• W4386458464 hasConcept C158787203 @default.
• W4386458464 hasConcept C162324750 @default.
• W4386458464 hasConcept C178790620 @default.
• W4386458464 hasConcept C185592680 @default.
• W4386458464 hasConcept C203032635 @default.
• W4386458464 hasConcept C2779345167 @default.
• W4386458464 hasConcept C39432304 @default.
• W4386458464 hasConcept C537208039 @default.
• W4386458464 hasConcept C540031477 @default.
• W4386458464 hasConcept C91586092 @default.
• W4386458464 hasConcept C91602232 @default.
• W4386458464 hasConceptScore W4386458464C105923489 @default.
• W4386458464 hasConceptScore W4386458464C106159729 @default.
• W4386458464 hasConceptScore W4386458464C107872376 @default.
• W4386458464 hasConceptScore W4386458464C113196181 @default.
• W4386458464 hasConceptScore W4386458464C127313418 @default.
• W4386458464 hasConceptScore W4386458464C149849071 @default.
• W4386458464 hasConceptScore W4386458464C158787203 @default.
• W4386458464 hasConceptScore W4386458464C162324750 @default.
• W4386458464 hasConceptScore W4386458464C178790620 @default.
• W4386458464 hasConceptScore W4386458464C185592680 @default.
• W4386458464 hasConceptScore W4386458464C203032635 @default.
• W4386458464 hasConceptScore W4386458464C2779345167 @default.
• W4386458464 hasConceptScore W4386458464C39432304 @default.
• W4386458464 hasConceptScore W4386458464C537208039 @default.
• W4386458464 hasConceptScore W4386458464C540031477 @default.
• W4386458464 hasConceptScore W4386458464C91586092 @default.
• W4386458464 hasConceptScore W4386458464C91602232 @default.
• W4386458464 hasFunder F4320321108 @default.
• W4386458464 hasFunder F4320322327 @default.
• W4386458464 hasFunder F4320338335 @default.
• W4386458464 hasLocation W43864584641 @default.
• W4386458464 hasOpenAccess W4386458464 @default.
• W4386458464 hasPrimaryLocation W43864584641 @default.
• W4386458464 hasRelatedWork W1512614458 @default.
• W4386458464 hasRelatedWork W2027613151 @default.
• W4386458464 hasRelatedWork W2128439374 @default.
• W4386458464 hasRelatedWork W2421510469 @default.
• W4386458464 hasRelatedWork W2526955845 @default.
• W4386458464 hasRelatedWork W2939525291 @default.
• W4386458464 hasRelatedWork W3158754751 @default.
• W4386458464 hasRelatedWork W3172737693 @default.
• W4386458464 hasRelatedWork W3205070264 @default.
• W4386458464 hasRelatedWork W3126136541 @default.
• W4386458464 isParatext "false" @default.

• next