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- W4386469207 abstract "A palladium(II)-catalyzed regio- and stereoselective difunctionalization of alkynoic acids has been achieved using sodium sulfinates and isocyanides to synthesize (E)-β-sulfonylacrylamides. The reaction proceeds via decarboxylative isocyanide addition, followed by sulfonylation. This three-component process works well with aromatic, heteroaromatic, and aliphatic alkynoic acids with good functional group tolerance and excellent regio- and stereoselectivity. DFT calculations were carried out to explain the reaction mechanism and the stereoselective formation of (E)-β-sulfonylacrylamides." @default.
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- W4386469207 date "2023-09-06" @default.
- W4386469207 modified "2023-09-30" @default.
- W4386469207 title "Palladium(II)-Catalyzed Decarboxylative Difunctionalization of Alkynoic Acids To Access (<i>E</i>)-β-Sulfonylacrylamides and DFT Study" @default.
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- W4386469207 doi "https://doi.org/10.1021/acs.orglett.3c02415" @default.
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