Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386470893> ?p ?o ?g. }
- W4386470893 endingPage "43677" @default.
- W4386470893 startingPage "43667" @default.
- W4386470893 abstract "While uranyl-based metal-organic frameworks (MOFs) boast impressive photocatalytic abilities, significant questions remain regarding their excitation pathways and methods to fine-tune their performance due to the lack of information regarding heterogeneous uranyl catalysis. Herein, we investigated how linker identity and photoexcitation impact uranyl photocatalysis when the uranyl coordination environment remains constant. Toward this end, we prepared three uranyl-based MOFs (NU-1301, NU-1307, and ZnTCPP-U2) and then examined the structural and photochemical properties of each through X-ray diffraction, X-ray absorption, and photoluminescence. We then correlated our observations to the photocatalytic performance for fluorination of cyclooctane. The excitation profile from NU-1301 and NU-1307 exhibited spin-forbidden linker transitions and uranyl vibronic progressions, with uranyl excitation and emission being most dominant in NU-1301. Consequently, NU-1301 was a more active photocatalyst than NU-1307. In contrast, the excitation profile from ZnTCPP-U2 contained transitions associated with the porphyrin linker exclusively. Photocatalytic activity from ZnTCPP-U2 significantly underperformed in comparison to that of the other two MOFs. These data suggest that linkers' photophysical properties can be used to predict the photocatalytic behavior of uranyl-containing MOFs." @default.
- W4386470893 created "2023-09-07" @default.
- W4386470893 creator A5004161217 @default.
- W4386470893 creator A5006761290 @default.
- W4386470893 creator A5017714289 @default.
- W4386470893 creator A5018869539 @default.
- W4386470893 creator A5019874172 @default.
- W4386470893 creator A5025860833 @default.
- W4386470893 creator A5033553445 @default.
- W4386470893 creator A5035962365 @default.
- W4386470893 creator A5072874908 @default.
- W4386470893 creator A5092761984 @default.
- W4386470893 date "2023-09-06" @default.
- W4386470893 modified "2023-10-14" @default.
- W4386470893 title "Influence of Linker Identity on the Photochemistry of Uranyl-Organic Frameworks" @default.
- W4386470893 cites W1964663048 @default.
- W4386470893 cites W1966107502 @default.
- W4386470893 cites W1971818787 @default.
- W4386470893 cites W1973783078 @default.
- W4386470893 cites W1989276354 @default.
- W4386470893 cites W2000445910 @default.
- W4386470893 cites W2017220615 @default.
- W4386470893 cites W2018222553 @default.
- W4386470893 cites W2035324351 @default.
- W4386470893 cites W2048109066 @default.
- W4386470893 cites W2056127514 @default.
- W4386470893 cites W2056456183 @default.
- W4386470893 cites W2057523617 @default.
- W4386470893 cites W2060121236 @default.
- W4386470893 cites W2062269633 @default.
- W4386470893 cites W2063445282 @default.
- W4386470893 cites W2070227796 @default.
- W4386470893 cites W2070782313 @default.
- W4386470893 cites W2082066417 @default.
- W4386470893 cites W2086249756 @default.
- W4386470893 cites W2141939342 @default.
- W4386470893 cites W2151347879 @default.
- W4386470893 cites W2160174308 @default.
- W4386470893 cites W2201506138 @default.
- W4386470893 cites W2470325395 @default.
- W4386470893 cites W2517182935 @default.
- W4386470893 cites W2526534388 @default.
- W4386470893 cites W2543940523 @default.
- W4386470893 cites W2606061412 @default.
- W4386470893 cites W2906440588 @default.
- W4386470893 cites W2951167172 @default.
- W4386470893 cites W3006871242 @default.
- W4386470893 cites W3007596581 @default.
- W4386470893 cites W3029418064 @default.
- W4386470893 cites W3042564991 @default.
- W4386470893 cites W3084235195 @default.
- W4386470893 cites W3095653097 @default.
- W4386470893 cites W3127385664 @default.
- W4386470893 cites W3193743532 @default.
- W4386470893 cites W3194840547 @default.
- W4386470893 cites W3216889639 @default.
- W4386470893 cites W4232465300 @default.
- W4386470893 doi "https://doi.org/10.1021/acsami.3c06897" @default.
- W4386470893 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37672765" @default.
- W4386470893 hasPublicationYear "2023" @default.
- W4386470893 type Work @default.
- W4386470893 citedByCount "0" @default.
- W4386470893 crossrefType "journal-article" @default.
- W4386470893 hasAuthorship W4386470893A5004161217 @default.
- W4386470893 hasAuthorship W4386470893A5006761290 @default.
- W4386470893 hasAuthorship W4386470893A5017714289 @default.
- W4386470893 hasAuthorship W4386470893A5018869539 @default.
- W4386470893 hasAuthorship W4386470893A5019874172 @default.
- W4386470893 hasAuthorship W4386470893A5025860833 @default.
- W4386470893 hasAuthorship W4386470893A5033553445 @default.
- W4386470893 hasAuthorship W4386470893A5035962365 @default.
- W4386470893 hasAuthorship W4386470893A5072874908 @default.
- W4386470893 hasAuthorship W4386470893A5092761984 @default.
- W4386470893 hasConcept C111919701 @default.
- W4386470893 hasConcept C121332964 @default.
- W4386470893 hasConcept C147789679 @default.
- W4386470893 hasConcept C150394285 @default.
- W4386470893 hasConcept C155220765 @default.
- W4386470893 hasConcept C161790260 @default.
- W4386470893 hasConcept C178790620 @default.
- W4386470893 hasConcept C179366358 @default.
- W4386470893 hasConcept C185592680 @default.
- W4386470893 hasConcept C191897082 @default.
- W4386470893 hasConcept C192562407 @default.
- W4386470893 hasConcept C2778468930 @default.
- W4386470893 hasConcept C2779480358 @default.
- W4386470893 hasConcept C2780557392 @default.
- W4386470893 hasConcept C41008148 @default.
- W4386470893 hasConcept C555451288 @default.
- W4386470893 hasConcept C62520636 @default.
- W4386470893 hasConcept C65165184 @default.
- W4386470893 hasConcept C75473681 @default.
- W4386470893 hasConcept C83581075 @default.
- W4386470893 hasConceptScore W4386470893C111919701 @default.
- W4386470893 hasConceptScore W4386470893C121332964 @default.
- W4386470893 hasConceptScore W4386470893C147789679 @default.
- W4386470893 hasConceptScore W4386470893C150394285 @default.
- W4386470893 hasConceptScore W4386470893C155220765 @default.