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- W4386471636 abstract "The first examples of tandem oxidative dearomatizations of 9,10-diphenylanthracene atropisomers with ortho,ortho′- formyl substituents are presented. In the presence of KMnO4, their stereoselective tandem double oxidation and spirocyclization mainly afford the syn or anti dearomatized 9,10-diphthalide anthracenes. Using Pinnick’s reagent and depending on the conditions, the oxidation can mainly lead to the corresponding syn or anti diacids in good yields or to three oxidation products. An unprecedented further oxidative ring expansion toward dibenzo[b,e]oxepines is also reported." @default.
- W4386471636 created "2023-09-07" @default.
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- W4386471636 date "2023-09-06" @default.
- W4386471636 modified "2023-09-30" @default.
- W4386471636 title "Tandem Oxidative Dearomatizations of Diphenylanthracene Atropisomers" @default.
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- W4386471636 doi "https://doi.org/10.1021/acs.joc.3c01252" @default.
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