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- W4386497995 abstract "The tetrasilyl‐substituted distannene, (tBu2HSi)2Sn=Sn(SiHtBu2)2 6, was synthesized by mild thermolysis (70°C in hexane) of tris(di‐tert‐butyl‐hydridosilyl)stannane 4. The X‐ray crystallography structure of 6 reveals the following unusual structural properties: a planar geometry around both Sn atoms (Σ∡Sn = 359.87°), a non‐twisted Sn=Sn double bond, and the shortest Sn=Sn double bond of 2.599 Å among all acyclic distannenes. Thus, compound 6 is the first reported distannene having a structure closely analogous to a classic alkene. Reactions of 6 with CCl4 or with 2,3‐dimethylbuta‐1,3‐diene to produce 1,2‐dichlorodistannane 9 and the [2+4] cycloadduct 10, respectively, are characteristic for a Sn=Sn double bond." @default.
- W4386497995 created "2023-09-07" @default.
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- W4386497995 date "2023-09-07" @default.
- W4386497995 modified "2023-10-16" @default.
- W4386497995 title "The First Planar, Not Twisted, Distannene – A Structural Alkene Analog. Synthesis, Isolation and X‐ray Crystallography Characterization" @default.
- W4386497995 doi "https://doi.org/10.1002/chem.202302678" @default.
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