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• W4386504760 startingPage "145938" @default.
• W4386504760 abstract "FePO4 precursors with manipulated morphology were prepared by adjusting aging acidity and reduced to generate LiFePO4/C for systematic exploration of intermediate influence. The characterization results indicated that FePO4 morphology could be regulated drastically from amorphous intermediate to hydro-crystalline flower-like aggregates and to ellipsoid shape crystals owing to incremental aging acidity, with accompanying graver agglomeration at excessively low pH. It was determined that stable LiFePO4/C originated from porous hydro-crystalline intermediate at moderate pH of the aging process would perform an advantageous low-current capacity. However, cathode material generated from amorphous intermediates under less acidic aging would behave more prominently at high rate, owing to better diffusion kinetics and charge transfer brought by minimized particle size and higher specific surface area of the porous structure. Besides, exasperated morphology with severe particle growth and agglomeration of intermediate at excessive aging acidity would lead to apparent weakening effect to electrochemical performance of LiFePO4/C with discharge capacity decreased." @default.
• W4386504760 created "2023-09-08" @default.
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• W4386504760 date "2023-10-01" @default.
• W4386504760 modified "2023-10-09" @default.
• W4386504760 title "Insight into intermediate impact of aging acidity and regulating mechanism on the performance of LiFePO4/C cathode material" @default.
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• W4386504760 doi "https://doi.org/10.1016/j.cej.2023.145938" @default.
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