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- W4386529530 abstract "The first coordination-saturated buckyball with a C60 molecule totally encased in an icosidodecahedral Cu30 in a (μ30 -(η2 )30 )-fashion, namely C60 @Cu30 @Cl36 N12 , has been successfully realized by a C60 -templated assembly. The 48 outmost coordinating atoms (36Cl+12N) comprise a new simple polyhedron that is described by a ccf topology. Charge transfer from (CuI , Cl) to C60 explains the expansion of the light absorption up to 700 nm, and accounts for an ultrafast photophysical process that underpins its high photothermal conversion efficiency. This work makes a giant step forward in exohedral metallofullerene (ExMF) chemistry." @default.
- W4386529530 created "2023-09-09" @default.
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- W4386529530 date "2023-09-18" @default.
- W4386529530 modified "2023-10-18" @default.
- W4386529530 title "Icosidodecahedral Coordination‐saturated Cuprofullerene" @default.
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- W4386529530 doi "https://doi.org/10.1002/anie.202312698" @default.
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