Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386548986> ?p ?o ?g. }
- W4386548986 endingPage "27065" @default.
- W4386548986 startingPage "27054" @default.
- W4386548986 abstract "The catalytic conversion of biomass-derived glycerol into high-value-added products, such as glyceric acid (GLYA), using catalyst-supported Au nanoparticles (Au NPs) at room temperature presents a significant challenge. In this study, we constructed a series of supported Au catalysts, including Au/ZrO2@C, Au/C, Au/ZrO2, and Au/ZrO2-C, and investigated their effectiveness in selectively catalytic oxidizing glycerol to GLYA at room temperature. Among these catalysts, the Au/ZrO2@C catalyst exhibited the best catalytic performance, achieving a glycerol conversion rate of 73% and a GLYA selectivity of 79% under the optimized reaction conditions (reaction conditions: 30 mL 0.1 M glycerol, glycerol/Au = 750 mol mol-1, T = 25 °C, p(O2) = 10 bar, stirring speed = 600 rpm, time = 6 h). Physical adsorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and other characterization methods were employed to analyze the texture properties of the catalyst. The findings indicated that the support structure, the strong metal-support interactions between Au NPs and the support, and the presence of small metallic Au NPs were the primary factors contributing to the catalyst's high activity and selectivity. Moreover, the reusability of the Au/ZrO2@C catalyst was investigated, and a probable reaction mechanism for the oxidation of glycerol was proposed." @default.
- W4386548986 created "2023-09-09" @default.
- W4386548986 creator A5029565945 @default.
- W4386548986 creator A5053452393 @default.
- W4386548986 creator A5074142371 @default.
- W4386548986 creator A5079990075 @default.
- W4386548986 creator A5080474994 @default.
- W4386548986 creator A5090735273 @default.
- W4386548986 date "2023-01-01" @default.
- W4386548986 modified "2023-10-14" @default.
- W4386548986 title "Heterogeneous catalytic oxidation of glycerol over a UiO-66-derived ZrO<sub>2</sub>@C supported Au catalyst at room temperature" @default.
- W4386548986 cites W1153622952 @default.
- W4386548986 cites W1742701672 @default.
- W4386548986 cites W1970481590 @default.
- W4386548986 cites W1976784016 @default.
- W4386548986 cites W1977683397 @default.
- W4386548986 cites W1978073671 @default.
- W4386548986 cites W1978381577 @default.
- W4386548986 cites W1979523591 @default.
- W4386548986 cites W1987535335 @default.
- W4386548986 cites W1989377396 @default.
- W4386548986 cites W1995004090 @default.
- W4386548986 cites W1998356091 @default.
- W4386548986 cites W2011288423 @default.
- W4386548986 cites W2024355474 @default.
- W4386548986 cites W2029842534 @default.
- W4386548986 cites W2034987712 @default.
- W4386548986 cites W2042995514 @default.
- W4386548986 cites W2045282826 @default.
- W4386548986 cites W2046578088 @default.
- W4386548986 cites W2065347927 @default.
- W4386548986 cites W2067095856 @default.
- W4386548986 cites W2086256185 @default.
- W4386548986 cites W2121215104 @default.
- W4386548986 cites W2141773818 @default.
- W4386548986 cites W2158585406 @default.
- W4386548986 cites W2170774098 @default.
- W4386548986 cites W2171599642 @default.
- W4386548986 cites W2232926208 @default.
- W4386548986 cites W2278563412 @default.
- W4386548986 cites W2324778723 @default.
- W4386548986 cites W2330960826 @default.
- W4386548986 cites W2331558376 @default.
- W4386548986 cites W2488813449 @default.
- W4386548986 cites W2511452911 @default.
- W4386548986 cites W2581148689 @default.
- W4386548986 cites W2594278309 @default.
- W4386548986 cites W2601879102 @default.
- W4386548986 cites W2607457567 @default.
- W4386548986 cites W2626830377 @default.
- W4386548986 cites W2725891045 @default.
- W4386548986 cites W2744873086 @default.
- W4386548986 cites W2790463927 @default.
- W4386548986 cites W2792027474 @default.
- W4386548986 cites W2795973855 @default.
- W4386548986 cites W2806143680 @default.
- W4386548986 cites W2899709317 @default.
- W4386548986 cites W2906606730 @default.
- W4386548986 cites W2949454678 @default.
- W4386548986 cites W2951128735 @default.
- W4386548986 cites W2969953269 @default.
- W4386548986 cites W2971771678 @default.
- W4386548986 cites W2978541484 @default.
- W4386548986 cites W2981701286 @default.
- W4386548986 cites W3013754189 @default.
- W4386548986 cites W3016696264 @default.
- W4386548986 cites W3131245016 @default.
- W4386548986 cites W3168621124 @default.
- W4386548986 doi "https://doi.org/10.1039/d3ra04300b" @default.
- W4386548986 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37693085" @default.
- W4386548986 hasPublicationYear "2023" @default.
- W4386548986 type Work @default.
- W4386548986 citedByCount "0" @default.
- W4386548986 crossrefType "journal-article" @default.
- W4386548986 hasAuthorship W4386548986A5029565945 @default.
- W4386548986 hasAuthorship W4386548986A5053452393 @default.
- W4386548986 hasAuthorship W4386548986A5074142371 @default.
- W4386548986 hasAuthorship W4386548986A5079990075 @default.
- W4386548986 hasAuthorship W4386548986A5080474994 @default.
- W4386548986 hasAuthorship W4386548986A5090735273 @default.
- W4386548986 hasBestOaLocation W43865489861 @default.
- W4386548986 hasConcept C118792377 @default.
- W4386548986 hasConcept C127413603 @default.
- W4386548986 hasConcept C155672457 @default.
- W4386548986 hasConcept C161790260 @default.
- W4386548986 hasConcept C171250308 @default.
- W4386548986 hasConcept C175708663 @default.
- W4386548986 hasConcept C178790620 @default.
- W4386548986 hasConcept C179104552 @default.
- W4386548986 hasConcept C185592680 @default.
- W4386548986 hasConcept C192562407 @default.
- W4386548986 hasConcept C2780881558 @default.
- W4386548986 hasConcept C42360764 @default.
- W4386548986 hasConcept C544153396 @default.
- W4386548986 hasConcept C77176794 @default.
- W4386548986 hasConceptScore W4386548986C118792377 @default.
- W4386548986 hasConceptScore W4386548986C127413603 @default.
- W4386548986 hasConceptScore W4386548986C155672457 @default.