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- W4386572393 abstract "It is anticipated to achieve safe, economical, and high-density hydrogen storage via hydrate, but sluggish formation kinetics of H2 hydrate and low hydrogen storage capacity limit its application, and appropriate kinetic promoters are required to improve the situation. In this work, three nano promoters were prepared by soap-free emulsion polymerization method, the functional groups of -SO3−, –COO− and -N(CH3)3+ were separately immobilized on nano spheres to produce the nano promoters of -SO3−@PSNS, –COO−@PSNS and -N(CH3)3+@PSNS, and their influence on the formation kinetics of mixed H2/THF hydrate was evaluated, while the performance of conventional kinetic promoters of methane hydrate was also estimated for comparison. It was found that the formation kinetics of mixed H2/THF hydrate was enhanced in the presence of nano promoters, which improve early growth of H2/THF hydrate and later water-to-hydrate conversion, leading to large hydrogen storage capacity. -SO3−@PSNS causes H2/THF hydrate to be looser and performs the best among the three nano promoters, hydrogen storage capacity in -SO3−@PSNS system is up to 0.467 wt% at 12 MPa, which increase by 39.8% comparing with that in pure THF system, and satisfactory hydrogen storage capacity of 0.303 wt% was also obtained under milder condition (7 MPa). For conventional kinetic promoters, L-methionine performs the best and shows similar promotion effect like -SO3−@PSNS, but it is excluded for large-scale industrial application when taking its high cost and perishable nature into consideration, whereas this scenario is improved by the proposed nano promoters." @default.
- W4386572393 created "2023-09-10" @default.
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- W4386572393 date "2023-10-01" @default.
- W4386572393 modified "2023-10-14" @default.
- W4386572393 title "Enhanced formation kinetics of mixed H2/THF hydrate in the presence of nano promoters" @default.
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- W4386572393 doi "https://doi.org/10.1016/j.cej.2023.145901" @default.
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