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- W4386603895 abstract "Using a commercially available potentiostat, the electrochemical synthesis of unnatural amino acids bearing heteroaromatics on the lateral chain has been accomplished. This strategy exploits the side-chain decarboxylative arylation of aspartic/glutamic acid, a reaction that becomes challenging with electron-rich coupling partners such as 5- and 6-membered heteroaromatics. These rings are underrepresented in unnatural amino acids, therefore it allowed a wider exploration of the chemical space, also given the abundance of the aryl bromides employable in this reaction" @default.
- W4386603895 created "2023-09-12" @default.
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- W4386603895 date "2023-09-11" @default.
- W4386603895 modified "2023-09-29" @default.
- W4386603895 title "Electrochemical Synthesis of Unnatural Amino Acids Embedding 5- and 6-Membered Heteroaromatics" @default.
- W4386603895 doi "https://doi.org/10.26434/chemrxiv-2023-nps5t" @default.
- W4386603895 hasPublicationYear "2023" @default.
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