Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386623906> ?p ?o ?g. }
- W4386623906 abstract "Copper nanoclusters (CuNCs) are emerging electrochemiluminescence (ECL) emitters with unique molecule-like electronic structures, high abundance, and low cost. However, the synthesis of CuNCs with high ECL efficiency and stability in a scalable manner remains challenging. Here, we report a facile gram-scale approach for preparing self-assembled CuNCs (CuNCsAssy ) induced by ligands with exceptionally boosted anodic ECL and stability. Compared to the disordered aggregates that are inactive in ECL, the CuNCsAssy shows a record anodic ECL efficiency for CuNCs (10 %, wavelength-corrected, relative to Ru(bpy)3 Cl2 /tripropylamine). Mechanism studies revealed the unusual dual functions of ligands in simultaneously facilitating electrochemical excitation and radiative transition. Moreover, the assembly addressed the limitation of poor stability of conventional CuNCs. As a proof of concept, an ECL biosensor for alkaline phosphatase detection was successfully constructed with an ultralow limit of detection of 8.1×10-6 U/L." @default.
- W4386623906 created "2023-09-13" @default.
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- W4386623906 date "2023-09-25" @default.
- W4386623906 modified "2023-10-10" @default.
- W4386623906 title "Ligand‐induced Assembly of Cu Nanoclusters with Enhanced Electrochemcial Excitation and Radiative Transition for Electrochemiluminescence" @default.
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- W4386623906 doi "https://doi.org/10.1002/anie.202312053" @default.
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