Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386630215> ?p ?o ?g. }
- W4386630215 endingPage "34556" @default.
- W4386630215 startingPage "34549" @default.
- W4386630215 abstract "A new class of highly active ethylene tri-/tetramerization chromium catalysts supported by iminophosphine ligands has been studied. The impact of electronic and steric changes of these ligands on selectivity and activity has been investigated by varying P- and/or N-substituents. Upon activation with MMAO, the ligand bearing a P-cyclohexyl group displayed a high activity of 307 kg/(g Cr/h) with a high trimerization selectivity of 92.6%. Decreasing the steric hindrance of N-aryl group led to a decrease in 1-hexene selectivity (74.5%), producing more 1-octene (10.3%). X-ray diffraction analysis verifies that the ligands coordinate with the chromium center in a κ2-P,N mode." @default.
- W4386630215 created "2023-09-13" @default.
- W4386630215 creator A5012675056 @default.
- W4386630215 creator A5012851776 @default.
- W4386630215 creator A5013397345 @default.
- W4386630215 creator A5048067117 @default.
- W4386630215 creator A5091032450 @default.
- W4386630215 date "2023-09-12" @default.
- W4386630215 modified "2023-10-17" @default.
- W4386630215 title "Chromium Ethylene Tri-/Tetramerization Catalysts Supported by Iminophosphine Ligands" @default.
- W4386630215 cites W1966825765 @default.
- W4386630215 cites W1972210880 @default.
- W4386630215 cites W1977770708 @default.
- W4386630215 cites W1978496396 @default.
- W4386630215 cites W1990643101 @default.
- W4386630215 cites W2004853118 @default.
- W4386630215 cites W2005667627 @default.
- W4386630215 cites W2013088669 @default.
- W4386630215 cites W2018897482 @default.
- W4386630215 cites W2025121079 @default.
- W4386630215 cites W2052572538 @default.
- W4386630215 cites W2054940179 @default.
- W4386630215 cites W2064371880 @default.
- W4386630215 cites W2065707019 @default.
- W4386630215 cites W2077718735 @default.
- W4386630215 cites W2078930137 @default.
- W4386630215 cites W2088042409 @default.
- W4386630215 cites W2091280774 @default.
- W4386630215 cites W2103547720 @default.
- W4386630215 cites W2103945489 @default.
- W4386630215 cites W2116776591 @default.
- W4386630215 cites W2118706140 @default.
- W4386630215 cites W2130611467 @default.
- W4386630215 cites W2130819699 @default.
- W4386630215 cites W2132716483 @default.
- W4386630215 cites W2132737175 @default.
- W4386630215 cites W2137846549 @default.
- W4386630215 cites W2138674999 @default.
- W4386630215 cites W2149465910 @default.
- W4386630215 cites W2153319171 @default.
- W4386630215 cites W2172052586 @default.
- W4386630215 cites W2253236134 @default.
- W4386630215 cites W2315071864 @default.
- W4386630215 cites W2316720314 @default.
- W4386630215 cites W2317398100 @default.
- W4386630215 cites W2324592695 @default.
- W4386630215 cites W2328109312 @default.
- W4386630215 cites W2328314931 @default.
- W4386630215 cites W2605411514 @default.
- W4386630215 cites W2617788545 @default.
- W4386630215 cites W2790554591 @default.
- W4386630215 cites W2887416048 @default.
- W4386630215 cites W2893331655 @default.
- W4386630215 cites W2896563696 @default.
- W4386630215 cites W2904703621 @default.
- W4386630215 cites W2911318053 @default.
- W4386630215 cites W2912059832 @default.
- W4386630215 cites W2921418738 @default.
- W4386630215 cites W2949071382 @default.
- W4386630215 cites W2953813268 @default.
- W4386630215 cites W2975805809 @default.
- W4386630215 cites W2990025620 @default.
- W4386630215 cites W2991083870 @default.
- W4386630215 cites W3097914689 @default.
- W4386630215 cites W3133648734 @default.
- W4386630215 cites W3204185664 @default.
- W4386630215 cites W3206212602 @default.
- W4386630215 cites W3211688276 @default.
- W4386630215 cites W4225310380 @default.
- W4386630215 cites W4281789198 @default.
- W4386630215 cites W4285300271 @default.
- W4386630215 cites W4288063971 @default.
- W4386630215 cites W4290860398 @default.
- W4386630215 cites W4293162434 @default.
- W4386630215 cites W4297989287 @default.
- W4386630215 cites W4300860375 @default.
- W4386630215 cites W4362607417 @default.
- W4386630215 doi "https://doi.org/10.1021/acsomega.3c03356" @default.
- W4386630215 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37780000" @default.
- W4386630215 hasPublicationYear "2023" @default.
- W4386630215 type Work @default.
- W4386630215 citedByCount "0" @default.
- W4386630215 crossrefType "journal-article" @default.
- W4386630215 hasAuthorship W4386630215A5012675056 @default.
- W4386630215 hasAuthorship W4386630215A5012851776 @default.
- W4386630215 hasAuthorship W4386630215A5013397345 @default.
- W4386630215 hasAuthorship W4386630215A5048067117 @default.
- W4386630215 hasAuthorship W4386630215A5091032450 @default.
- W4386630215 hasBestOaLocation W43866302151 @default.
- W4386630215 hasConcept C116569031 @default.
- W4386630215 hasConcept C118792377 @default.
- W4386630215 hasConcept C155647269 @default.
- W4386630215 hasConcept C161790260 @default.
- W4386630215 hasConcept C170493617 @default.
- W4386630215 hasConcept C178790620 @default.
- W4386630215 hasConcept C185592680 @default.
- W4386630215 hasConcept C201194858 @default.
- W4386630215 hasConcept C2778597550 @default.