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- W4386687466 abstract "In this work, we report the ternary Cu-based chalcogenide, Cu2TiTe3, as a promising thermoelectric material in middle-temperature range. The bonding interaction between Te p and Ti d states is observed in the Ti–Te octahedron, which drives the side bands up converging with Γ band, yielding a high valence band degeneracy of 5. A high electronic quality factor of 2.2 μW cm−1 K−2 and a decent power factor of 7.5 μW cm−1 K−2 at 300 K are achieved for Cu2TiTe3. Likewise, Cu2TiTe3 demonstrates low lattice thermal conductivity throughout the measured temperature range, which is attributed to the low frequency vibration related to the global motion of Ti–Te–Cu clusters. Finally, a maximum figure-of-merit of 0.38 was obtained for Cu2TiTe3 at 600 K." @default.
- W4386687466 created "2023-09-13" @default.
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- W4386687466 date "2023-09-11" @default.
- W4386687466 modified "2023-10-18" @default.
- W4386687466 title "Thermoelectric performance of ternary Cu-based chalcogenide Cu2TiTe3" @default.
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- W4386687466 doi "https://doi.org/10.1063/5.0167921" @default.
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