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• W4386736231 abstract "A new approach is proposed for the divergent and regioselective synthesis of (E)-2-bromo-1-phenylvinyl trifluoromethanesulfonates through alkyne difunctionalization by employing a compatible system of abundantly available alkynes, N-bromosuccinimide (NBS), and trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed by ruthenium(III) acetate [Ru(OAc)3]. It is a novel method for the preparation of vinyl triflate and it offers a fundamental basis for the development of advanced functional compounds, including drugs and organic functional materials. Unlike previously reported methods, the proposed protocol can tolerate a broad range of functional groups. Alkynes derived from bioactive molecules, such as l(-)-borneol, demonstrate the potential value of this new reaction in organic synthesis." @default.
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• W4386736231 date "2023-09-14" @default.
• W4386736231 modified "2023-10-14" @default.
• W4386736231 title "Ru(OAc)₃-Catalyzed Regioselective Difunctionalization of Alkynes: Access to (<i>E</i>)-2-Bromo-1-alkenyl Sulfonates" @default.
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• W4386736231 doi "https://doi.org/10.1021/acs.orglett.3c02623" @default.
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