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• W4386750010 abstract "A library of 19 differently substituted 3-iodoindoles is generated by a consecutive four-component reaction starting from ortho-haloanilines, terminal alkynes, N-iodosuccinimide, and alkyl halides in yields of 11-69%. Initiated by a copper-free alkynylation, followed by a base-catalyzed cyclizive indole formation, electrophilic iodination, and finally electrophilic trapping of the intermediary indole anion with alkyl halides provides a concise one-pot synthesis of 3-iodoindoles. The latter are valuable substrates for Suzuki arylations, which are exemplified with the syntheses of four derivatives, some of them are blue emitters in solution and in the solid state, in good yield." @default.
• W4386750010 created "2023-09-15" @default.
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• W4386750010 date "2023-09-14" @default.
• W4386750010 modified "2023-09-29" @default.
• W4386750010 title "Consecutive four-component synthesis of trisubstituted 3-iodoindoles by an alkynylation–cyclization–iodination–alkylation sequence" @default.
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• W4386750010 doi "https://doi.org/10.3762/bjoc.19.99" @default.
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