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- W4386757466 abstract "Photoisomerization of retinal is pivotal to ion translocation across the bacterial membrane and has served as an inspiration for the development of artificial molecular switches and machines. Light-driven synthetic systems in which a macrocyclic component transits along a nonsymmetric axle in a specific direction have been reported; however, unidirectional and repetitive translocation of protons has not been achieved. Herein, we describe a unique protonation-controlled isomerization behavior for hemi-indigo dyes bearing N-heterocycles, featuring intramolecular hydrogen bonds. Light-induced isomerization from the Z to E isomer is unlocked when protonated, while reverse E → Z photoisomerization occurs in the neutral state. As a consequence, associated protons are displaced in a preferred direction with respect to the photoswitchable scaffold. These results will prove to be critical in developing artificial systems in which concentration gradients can be effectively generated using (solar) light energy." @default.
- W4386757466 created "2023-09-16" @default.
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- W4386757466 date "2023-09-15" @default.
- W4386757466 modified "2023-10-17" @default.
- W4386757466 title "Monodirectional Photocycle Drives Proton Translocation" @default.
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- W4386757466 doi "https://doi.org/10.1021/jacs.3c06587" @default.
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