Matches in SemOpenAlex for { <https://semopenalex.org/work/W4386758001> ?p ?o ?g. }
- W4386758001 abstract "Unusual behavior in solids emerges from the complex interplay between crystalline order, composition, and dimensionality. In crystals comprising weakly bound one-dimensional (1D) or quasi-1D (q-1D) chains, properties such as charge density waves, topologically protected states, and indirect-to-direct band gap crossovers have been predicted to arise. However, the experimental demonstration of many of these nascent physics in 1D or q-1D van der Waals (vdW) crystals is obscured by the highly anisotropic bonding between the chains, stochasticity of top-down exfoliation, and the lack of synthetic strategies to control bottom-up growth. Herein, we report the directed crystallization of a model q-1D vdW phase, Sb2S3, into dimensionally resolved nanostructures. We demonstrate the uncatalyzed growth of highly crystalline Sb2S3 nanowires, nanoribbons, and quasi-2D nanosheets with thicknesses in the range of 10 to 100 nm from the bottom-up crystallization of [Sb4S6]n chains. We found that dimensionally resolved nanostructures emerge from two distinct chemical vapor growth pathways defined by diverse covalent intrachain and anisotropic vdW interchain interactions and controlled precursor ratios in the vapor phase. At sub-100 nm nanostructure thicknesses, we observe the hardening of phonon modes, blue-shifting of optical band gaps, and the emergence of a new high-energy photoluminescence peak. The directional growth of weakly bound 1D ribbons or chains into well-resolved nanocrystalline morphologies provides opportunities to develop ordered nanostructures and hierarchical assemblies that are suitable for a wide range of optoelectronic and quantum devices." @default.
- W4386758001 created "2023-09-16" @default.
- W4386758001 creator A5015361534 @default.
- W4386758001 creator A5039410890 @default.
- W4386758001 creator A5041199467 @default.
- W4386758001 creator A5065310076 @default.
- W4386758001 creator A5085686503 @default.
- W4386758001 date "2023-09-15" @default.
- W4386758001 modified "2023-09-26" @default.
- W4386758001 title "Anisotropy-Driven Crystallization of Dimensionally Resolved Quasi-1D Van der Waals Nanostructures" @default.
- W4386758001 cites W1497702560 @default.
- W4386758001 cites W1586371271 @default.
- W4386758001 cites W1601528839 @default.
- W4386758001 cites W1747676264 @default.
- W4386758001 cites W1876133643 @default.
- W4386758001 cites W2003889004 @default.
- W4386758001 cites W2012705864 @default.
- W4386758001 cites W2014935324 @default.
- W4386758001 cites W2017871657 @default.
- W4386758001 cites W2020414709 @default.
- W4386758001 cites W2023579904 @default.
- W4386758001 cites W2043979991 @default.
- W4386758001 cites W2050022231 @default.
- W4386758001 cites W2052565695 @default.
- W4386758001 cites W2053084773 @default.
- W4386758001 cites W2077702579 @default.
- W4386758001 cites W2079337789 @default.
- W4386758001 cites W2080444100 @default.
- W4386758001 cites W2092443323 @default.
- W4386758001 cites W2105157003 @default.
- W4386758001 cites W2118492507 @default.
- W4386758001 cites W2131398376 @default.
- W4386758001 cites W2132682537 @default.
- W4386758001 cites W2148226925 @default.
- W4386758001 cites W2258548400 @default.
- W4386758001 cites W2290594521 @default.
- W4386758001 cites W2316629727 @default.
- W4386758001 cites W2335370736 @default.
- W4386758001 cites W2508920067 @default.
- W4386758001 cites W2516127619 @default.
- W4386758001 cites W2527844586 @default.
- W4386758001 cites W2543624893 @default.
- W4386758001 cites W2558813636 @default.
- W4386758001 cites W2580655056 @default.
- W4386758001 cites W2592161661 @default.
- W4386758001 cites W2592719236 @default.
- W4386758001 cites W2744024286 @default.
- W4386758001 cites W2767580334 @default.
- W4386758001 cites W2787199764 @default.
- W4386758001 cites W2793369479 @default.
- W4386758001 cites W2802616565 @default.
- W4386758001 cites W2886211001 @default.
- W4386758001 cites W2902113920 @default.
- W4386758001 cites W2952464912 @default.
- W4386758001 cites W2983105526 @default.
- W4386758001 cites W2987432019 @default.
- W4386758001 cites W3000852548 @default.
- W4386758001 cites W3004159920 @default.
- W4386758001 cites W3021999567 @default.
- W4386758001 cites W3037350787 @default.
- W4386758001 cites W3043050419 @default.
- W4386758001 cites W3083452753 @default.
- W4386758001 cites W3091801557 @default.
- W4386758001 cites W3100783706 @default.
- W4386758001 cites W3112676957 @default.
- W4386758001 cites W3123890503 @default.
- W4386758001 cites W3124775566 @default.
- W4386758001 cites W3125061208 @default.
- W4386758001 cites W3162746657 @default.
- W4386758001 cites W3164160941 @default.
- W4386758001 cites W3171500982 @default.
- W4386758001 cites W3182390394 @default.
- W4386758001 cites W3199112985 @default.
- W4386758001 cites W3207973228 @default.
- W4386758001 cites W3213969202 @default.
- W4386758001 cites W4225014812 @default.
- W4386758001 cites W4225104624 @default.
- W4386758001 cites W4240432736 @default.
- W4386758001 cites W4281773863 @default.
- W4386758001 cites W4285386949 @default.
- W4386758001 cites W4313812455 @default.
- W4386758001 cites W4320474879 @default.
- W4386758001 cites W912184481 @default.
- W4386758001 doi "https://doi.org/10.1021/jacs.3c05887" @default.
- W4386758001 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37713247" @default.
- W4386758001 hasPublicationYear "2023" @default.
- W4386758001 type Work @default.
- W4386758001 citedByCount "0" @default.
- W4386758001 crossrefType "journal-article" @default.
- W4386758001 hasAuthorship W4386758001A5015361534 @default.
- W4386758001 hasAuthorship W4386758001A5039410890 @default.
- W4386758001 hasAuthorship W4386758001A5041199467 @default.
- W4386758001 hasAuthorship W4386758001A5065310076 @default.
- W4386758001 hasAuthorship W4386758001A5085686503 @default.
- W4386758001 hasBestOaLocation W43867580011 @default.
- W4386758001 hasConcept C120665830 @default.
- W4386758001 hasConcept C121332964 @default.
- W4386758001 hasConcept C126061179 @default.
- W4386758001 hasConcept C159467904 @default.
- W4386758001 hasConcept C171250308 @default.